Synthesis, crystal structure, and nonlinear optical properties of Li 6CuB4O10: A congruently melting compound with isolated [CuB4O10]6- units

Shilie Pan, Jared P. Smit, Byron Watkins, Michael R. Marvel, Charlotte L. Stern, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

206 Citations (Scopus)

Abstract

Single crystals of Li6CuB4O10 have been synthesized, and its crystal structure has been determined. Li 6CuB4O10 crystallizes in the non-centrosymmetric triclinic space group P1 (No. 1). The structure consists of isolated [CuB4O10]6- polyanions that are bridged by six LiO4 tetrahedra. Li6CuB4O 10 is a congruently melting compound. It produces SHG intensity similar to that produced by KH2PO4 and is phase-matchable.

Original languageEnglish
Pages (from-to)11631-11634
Number of pages4
JournalJournal of the American Chemical Society
Volume128
Issue number35
DOIs
Publication statusPublished - Sep 6 2006

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Freezing
Melting
Optical properties
Crystal structure
Single crystals
polyanions

ASJC Scopus subject areas

  • Chemistry(all)

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Synthesis, crystal structure, and nonlinear optical properties of Li 6CuB4O10 : A congruently melting compound with isolated [CuB4O10]6- units. / Pan, Shilie; Smit, Jared P.; Watkins, Byron; Marvel, Michael R.; Stern, Charlotte L.; Poeppelmeier, Kenneth R.

In: Journal of the American Chemical Society, Vol. 128, No. 35, 06.09.2006, p. 11631-11634.

Research output: Contribution to journalArticle

Pan, Shilie ; Smit, Jared P. ; Watkins, Byron ; Marvel, Michael R. ; Stern, Charlotte L. ; Poeppelmeier, Kenneth R. / Synthesis, crystal structure, and nonlinear optical properties of Li 6CuB4O10 : A congruently melting compound with isolated [CuB4O10]6- units. In: Journal of the American Chemical Society. 2006 ; Vol. 128, No. 35. pp. 11631-11634.
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