Synthesis of 1,4,7-triphenyl-1,4,7-triphosphacyclononane

The first metal-free synthesis of a [9]-aneP3R3 ring

Daniel J. Lowry, Monte Helm

Research output: Contribution to journal › Article

12 Citations (Scopus)

Abstract

The 1,4,7-triphenyl-1,4,7-triphosphacyclononane ([9]-aneP 3Ph3) macrocycle was synthesized through the reaction of lithium bis(2-phenylphosphidoethyl)phenylphosphine with 1,2-dichloroethane. [9]-aneP3Ph3 was subsequently coordinated to a Mo metal center and isolated as the fac-Mo([9]-aneP3Ph3)(CO) 3 metal complex.

Original languageEnglish
Pages (from-to)4732-4734
Number of pages3
JournalInorganic Chemistry
Volume49
Issue number11
DOIs
Publication statusPublished - Jun 7 2010

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Coordination Complexes
Carbon Monoxide
Lithium
Metals
rings
synthesis
metals
lithium
1,4,7-triphenyl-1,4,7-triphosphacyclononane
ethylene dichloride

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Synthesis of 1,4,7-triphenyl-1,4,7-triphosphacyclononane : The first metal-free synthesis of a [9]-aneP3R3 ring. / Lowry, Daniel J.; Helm, Monte.

In: Inorganic Chemistry, Vol. 49, No. 11, 07.06.2010, p. 4732-4734.

Research output: Contribution to journal › Article

Lowry, DJ & Helm, M 2010, 'Synthesis of 1,4,7-triphenyl-1,4,7-triphosphacyclononane: The first metal-free synthesis of a [9]-aneP3R3 ring', Inorganic Chemistry, vol. 49, no. 11, pp. 4732-4734. https://doi.org/10.1021/ic100274m
Lowry DJ, Helm M. Synthesis of 1,4,7-triphenyl-1,4,7-triphosphacyclononane: The first metal-free synthesis of a [9]-aneP3R3 ring. Inorganic Chemistry. 2010 Jun 7;49(11):4732-4734. https://doi.org/10.1021/ic100274m
Lowry, Daniel J. ; Helm, Monte. / Synthesis of 1,4,7-triphenyl-1,4,7-triphosphacyclononane : The first metal-free synthesis of a [9]-aneP3R3 ring. In: Inorganic Chemistry. 2010 ; Vol. 49, No. 11. pp. 4732-4734.
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