Synthesis of 1,4,7-triphenyl-1,4,7-triphosphacyclononane: The first metal-free synthesis of a [9]-aneP3R3 ring

Daniel J. Lowry; Monte L. Helm

doi:10.1021/ic100274m

Synthesis of 1,4,7-triphenyl-1,4,7-triphosphacyclononane: The first metal-free synthesis of a [9]-aneP₃R₃ ring

Daniel J. Lowry, Monte L. Helm

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The 1,4,7-triphenyl-1,4,7-triphosphacyclononane ([9]-aneP ₃Ph₃) macrocycle was synthesized through the reaction of lithium bis(2-phenylphosphidoethyl)phenylphosphine with 1,2-dichloroethane. [9]-aneP₃Ph₃ was subsequently coordinated to a Mo metal center and isolated as the fac-Mo([9]-aneP₃Ph₃)(CO) ₃ metal complex.

Original language	English
Pages (from-to)	4732-4734
Number of pages	3
Journal	Inorganic Chemistry
Volume	49
Issue number	11
DOIs	https://doi.org/10.1021/ic100274m
Publication status	Published - Jun 7 2010

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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abstract = "The 1,4,7-triphenyl-1,4,7-triphosphacyclononane ([9]-aneP 3Ph3) macrocycle was synthesized through the reaction of lithium bis(2-phenylphosphidoethyl)phenylphosphine with 1,2-dichloroethane. [9]-aneP3Ph3 was subsequently coordinated to a Mo metal center and isolated as the fac-Mo([9]-aneP3Ph3)(CO) 3 metal complex.",

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T2 - The first metal-free synthesis of a [9]-aneP3R3 ring

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AU - Helm, Monte L.

PY - 2010/6/7

Y1 - 2010/6/7

N2 - The 1,4,7-triphenyl-1,4,7-triphosphacyclononane ([9]-aneP 3Ph3) macrocycle was synthesized through the reaction of lithium bis(2-phenylphosphidoethyl)phenylphosphine with 1,2-dichloroethane. [9]-aneP3Ph3 was subsequently coordinated to a Mo metal center and isolated as the fac-Mo([9]-aneP3Ph3)(CO) 3 metal complex.

AB - The 1,4,7-triphenyl-1,4,7-triphosphacyclononane ([9]-aneP 3Ph3) macrocycle was synthesized through the reaction of lithium bis(2-phenylphosphidoethyl)phenylphosphine with 1,2-dichloroethane. [9]-aneP3Ph3 was subsequently coordinated to a Mo metal center and isolated as the fac-Mo([9]-aneP3Ph3)(CO) 3 metal complex.

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