Synthesis of catalytically active porous organic polymers from metalloporphyrin building blocks

Abraham M. Shultz, Omar K. Farha, Joseph T Hupp, SonBinh T. Nguyen

Research output: Contribution to journalArticle

134 Citations (Scopus)

Abstract

The synthesis of a porous organic polymer (POP) containing free-base porphyrin subunits has been accomplished by the condensation of a bis(phthalic acid)porphyrin with tetra(4-aminophenyl)methane. Metallation by post-synthesis modification affords microporous materials incorporating either Fe or Mn(porphyrins) that have been shown to be active catalysts for both olefin epoxidation and alkane hydroxylation.

Original languageEnglish
Pages (from-to)686-689
Number of pages4
JournalChemical Science
Volume2
Issue number4
DOIs
Publication statusPublished - 2011

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Metalloporphyrins
Organic polymers
Porphyrins
Microporous materials
Hydroxylation
Alkanes
Epoxidation
Methane
Alkenes
Condensation
Catalysts

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Synthesis of catalytically active porous organic polymers from metalloporphyrin building blocks. / Shultz, Abraham M.; Farha, Omar K.; Hupp, Joseph T; Nguyen, SonBinh T.

In: Chemical Science, Vol. 2, No. 4, 2011, p. 686-689.

Research output: Contribution to journalArticle

Shultz, Abraham M. ; Farha, Omar K. ; Hupp, Joseph T ; Nguyen, SonBinh T. / Synthesis of catalytically active porous organic polymers from metalloporphyrin building blocks. In: Chemical Science. 2011 ; Vol. 2, No. 4. pp. 686-689.
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