Abstract
Comb polyelectrolytes consisting of a polysiloxane backbone with tetraglyme and lithium-sulfonate terminated perfluoroether side chains have been synthesized. Both types of side chains were independently prepared with allyl functionality and attached to poly(methylhydrosiloxane) by hydrosilylation. Several methods are described to form lithium sulfonate from sulfonate esters. Spectroscopic and thermal characterizations of the resulting polyelectrolyte are described.
| Original language | English |
|---|---|
| Pages (from-to) | 4223-4230 |
| Number of pages | 8 |
| Journal | Chemistry of Materials |
| Volume | 15 |
| Issue number | 22 |
| DOIs | |
| Publication status | Published - Nov 4 2003 |
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ASJC Scopus subject areas
- Materials Chemistry
- Materials Science(all)
Cite this
Synthesis of Comb Polysiloxane Polyelectrolytes Containing Oligoether and Perfluoroether Side Chains. / Snyder, J. F.; Hutchison, J. C.; Ratner, Mark A; Shriver, D. F.
In: Chemistry of Materials, Vol. 15, No. 22, 04.11.2003, p. 4223-4230.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Synthesis of Comb Polysiloxane Polyelectrolytes Containing Oligoether and Perfluoroether Side Chains
AU - Snyder, J. F.
AU - Hutchison, J. C.
AU - Ratner, Mark A
AU - Shriver, D. F.
PY - 2003/11/4
Y1 - 2003/11/4
N2 - Comb polyelectrolytes consisting of a polysiloxane backbone with tetraglyme and lithium-sulfonate terminated perfluoroether side chains have been synthesized. Both types of side chains were independently prepared with allyl functionality and attached to poly(methylhydrosiloxane) by hydrosilylation. Several methods are described to form lithium sulfonate from sulfonate esters. Spectroscopic and thermal characterizations of the resulting polyelectrolyte are described.
AB - Comb polyelectrolytes consisting of a polysiloxane backbone with tetraglyme and lithium-sulfonate terminated perfluoroether side chains have been synthesized. Both types of side chains were independently prepared with allyl functionality and attached to poly(methylhydrosiloxane) by hydrosilylation. Several methods are described to form lithium sulfonate from sulfonate esters. Spectroscopic and thermal characterizations of the resulting polyelectrolyte are described.
UR - http://www.scopus.com/inward/record.url?scp=0242489146&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0242489146&partnerID=8YFLogxK
U2 - 10.1021/cm0217396
DO - 10.1021/cm0217396
M3 - Article
AN - SCOPUS:0242489146
VL - 15
SP - 4223
EP - 4230
JO - Chemistry of Materials
JF - Chemistry of Materials
SN - 0897-4756
IS - 22
ER -