Synthesis of Comb Polysiloxane Polyelectrolytes Containing Oligoether and Perfluoroether Side Chains

J. F. Snyder, J. C. Hutchison, Mark A Ratner, D. F. Shriver

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

Comb polyelectrolytes consisting of a polysiloxane backbone with tetraglyme and lithium-sulfonate terminated perfluoroether side chains have been synthesized. Both types of side chains were independently prepared with allyl functionality and attached to poly(methylhydrosiloxane) by hydrosilylation. Several methods are described to form lithium sulfonate from sulfonate esters. Spectroscopic and thermal characterizations of the resulting polyelectrolyte are described.

Original languageEnglish
Pages (from-to)4223-4230
Number of pages8
JournalChemistry of Materials
Volume15
Issue number22
DOIs
Publication statusPublished - Nov 4 2003

Fingerprint

Siloxanes
Polyelectrolytes
Lithium
Silicones
Hydrosilylation
Esters
Hot Temperature
poly(methylhydrosiloxane)
tetraglyme

ASJC Scopus subject areas

  • Materials Chemistry
  • Materials Science(all)

Cite this

Synthesis of Comb Polysiloxane Polyelectrolytes Containing Oligoether and Perfluoroether Side Chains. / Snyder, J. F.; Hutchison, J. C.; Ratner, Mark A; Shriver, D. F.

In: Chemistry of Materials, Vol. 15, No. 22, 04.11.2003, p. 4223-4230.

Research output: Contribution to journalArticle

Snyder, J. F. ; Hutchison, J. C. ; Ratner, Mark A ; Shriver, D. F. / Synthesis of Comb Polysiloxane Polyelectrolytes Containing Oligoether and Perfluoroether Side Chains. In: Chemistry of Materials. 2003 ; Vol. 15, No. 22. pp. 4223-4230.
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