Abstract
The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.
| Original language | English |
|---|---|
| Pages (from-to) | 11722-11725 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 139 |
| Issue number | 34 |
| DOIs | |
| Publication status | Published - Aug 30 2017 |
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ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex. / Espinosa-Jalapa, Noel Angel; Kumar, Amit; Leitus, Gregory; Diskin-Posner, Yael; Milstein, David.
In: Journal of the American Chemical Society, Vol. 139, No. 34, 30.08.2017, p. 11722-11725.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex
AU - Espinosa-Jalapa, Noel Angel
AU - Kumar, Amit
AU - Leitus, Gregory
AU - Diskin-Posner, Yael
AU - Milstein, David
PY - 2017/8/30
Y1 - 2017/8/30
N2 - The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.
AB - The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.
UR - http://www.scopus.com/inward/record.url?scp=85028685210&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85028685210&partnerID=8YFLogxK
U2 - 10.1021/jacs.7b08341
DO - 10.1021/jacs.7b08341
M3 - Article
AN - SCOPUS:85028685210
VL - 139
SP - 11722
EP - 11725
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 34
ER -