Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex

Noel Angel Espinosa-Jalapa, Amit Kumar, Gregory Leitus, Yael Diskin-Posner, David Milstein

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.

Original languageEnglish
Pages (from-to)11722-11725
Number of pages4
JournalJournal of the American Chemical Society
Volume139
Issue number34
DOIs
Publication statusPublished - Aug 30 2017

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Imides
Manganese
Amines
Byproducts
Hydrogen
Gases
Metals
Earth (planet)
Atoms

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex. / Espinosa-Jalapa, Noel Angel; Kumar, Amit; Leitus, Gregory; Diskin-Posner, Yael; Milstein, David.

In: Journal of the American Chemical Society, Vol. 139, No. 34, 30.08.2017, p. 11722-11725.

Research output: Contribution to journalArticle

Espinosa-Jalapa, Noel Angel ; Kumar, Amit ; Leitus, Gregory ; Diskin-Posner, Yael ; Milstein, David. / Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex. In: Journal of the American Chemical Society. 2017 ; Vol. 139, No. 34. pp. 11722-11725.
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