Abstract
The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.
| Original language | English |
|---|---|
| Pages (from-to) | 11722-11725 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 139 |
| Issue number | 34 |
| DOIs | |
| Publication status | Published - Aug 30 2017 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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Cite this
Espinosa-Jalapa, N. A., Kumar, A., Leitus, G., Diskin-Posner, Y., & Milstein, D. (2017). Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex. Journal of the American Chemical Society, 139(34), 11722-11725. https://doi.org/10.1021/jacs.7b08341