TY - JOUR
T1 - Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex
AU - Espinosa-Jalapa, Noel Angel
AU - Kumar, Amit
AU - Leitus, Gregory
AU - Diskin-Posner, Yael
AU - Milstein, David
N1 - Funding Information:
This research was supported by the European Research Council (ERC AdG 692775). D.M. holds the Israel Matz Professorial Chair of Organic Chemistry. N.A.E.-J. thanks Mr. Armando Jinich for a postdoctoral fellowship. A.K. is thankful to the Israel Planning and Budgeting Commission (PBC) for a fellowship.
PY - 2017/8/30
Y1 - 2017/8/30
N2 - The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.
AB - The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.
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U2 - 10.1021/jacs.7b08341
DO - 10.1021/jacs.7b08341
M3 - Article
C2 - 28795820
AN - SCOPUS:85028685210
VL - 139
SP - 11722
EP - 11725
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 34
ER -