Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net

Significant enhancement in the degradation of a nerve agent simulant

Peng Li, Rachel C. Klet, Su Young Moon, Timothy C. Wang, Pravas Deria, Aaron W. Peters, Benjamin M. Klahr, Hea Jung Park, Salih S. Al-Juaid, Joseph T Hupp, Omar K. Farha

Research output: Contribution to journalArticle

65 Citations (Scopus)

Abstract

The synthesis of nano-sized particles of NU-1000 (length from 75 nm to 1200 nm) and PCN-222/MOF-545 (length from 350 nm to 900 nm) is reported. The catalytic hydrolysis of methyl paraoxon was investigated as a function of NU-1000 crystallite size and a significant enhancement in the rate was observed for the nano-sized crystals compared to microcrystals.

Original languageEnglish
Pages (from-to)10925-10928
Number of pages4
JournalChemical Communications
Volume51
Issue number54
DOIs
Publication statusPublished - Jul 11 2015

Fingerprint

Pregnenolone Carbonitrile
Microcrystals
Crystallite size
Nanocrystals
Hydrolysis
Metals
Degradation
Crystals
methylparaoxon
Nerve Agents

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net : Significant enhancement in the degradation of a nerve agent simulant. / Li, Peng; Klet, Rachel C.; Moon, Su Young; Wang, Timothy C.; Deria, Pravas; Peters, Aaron W.; Klahr, Benjamin M.; Park, Hea Jung; Al-Juaid, Salih S.; Hupp, Joseph T; Farha, Omar K.

In: Chemical Communications, Vol. 51, No. 54, 11.07.2015, p. 10925-10928.

Research output: Contribution to journalArticle

Li, P, Klet, RC, Moon, SY, Wang, TC, Deria, P, Peters, AW, Klahr, BM, Park, HJ, Al-Juaid, SS, Hupp, JT & Farha, OK 2015, 'Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net: Significant enhancement in the degradation of a nerve agent simulant', Chemical Communications, vol. 51, no. 54, pp. 10925-10928. https://doi.org/10.1039/c5cc03398e
Li, Peng ; Klet, Rachel C. ; Moon, Su Young ; Wang, Timothy C. ; Deria, Pravas ; Peters, Aaron W. ; Klahr, Benjamin M. ; Park, Hea Jung ; Al-Juaid, Salih S. ; Hupp, Joseph T ; Farha, Omar K. / Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net : Significant enhancement in the degradation of a nerve agent simulant. In: Chemical Communications. 2015 ; Vol. 51, No. 54. pp. 10925-10928.
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