Synthesis, properties, and gas separation studies of a robust diimide-based microporous organic polymer

Omar K. Farha, Alexander M. Spokoyny, Brad G. Hauser, Youn Sang Bae, Samantha E. Brown, Randall Q. Snurr, Chad A. Mirkin, Joseph T Hupp

Research output: Contribution to journalArticle

221 Citations (Scopus)

Abstract

The synthesis of a new porous organic polymer that features high surface area and pores of appropriate size and composition to capture CO 2 from mixtures with methane, was reported. The desired micro-and ultramicro-porosity was engendered by using a tetrahedral building block that is expected to produce a three-dimensional network. Single component adsorption isotherms for CO 2 and CH 4 were measured volumetrically for diimide subunits heated under a vacuum at 160°C. The selectivities for CO 2 CH 4 mixtures were calculated using ideal adsorbed solution theory (IAST). The first of these new materials, simply made from inexpensive precursors, shows outstanding thermal and chemical stability, and exceptional promise for CO 2 CH 4 separation.

Original languageEnglish
Pages (from-to)3033-3035
Number of pages3
JournalChemistry of Materials
Volume21
Issue number14
DOIs
Publication statusPublished - Jul 28 2009

Fingerprint

Organic polymers
Carbon Monoxide
Gases
Chemical stability
Adsorption isotherms
Methane
Thermodynamic stability
Porosity
Vacuum
Chemical analysis

ASJC Scopus subject areas

  • Materials Chemistry
  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Synthesis, properties, and gas separation studies of a robust diimide-based microporous organic polymer. / Farha, Omar K.; Spokoyny, Alexander M.; Hauser, Brad G.; Bae, Youn Sang; Brown, Samantha E.; Snurr, Randall Q.; Mirkin, Chad A.; Hupp, Joseph T.

In: Chemistry of Materials, Vol. 21, No. 14, 28.07.2009, p. 3033-3035.

Research output: Contribution to journalArticle

Farha, OK, Spokoyny, AM, Hauser, BG, Bae, YS, Brown, SE, Snurr, RQ, Mirkin, CA & Hupp, JT 2009, 'Synthesis, properties, and gas separation studies of a robust diimide-based microporous organic polymer', Chemistry of Materials, vol. 21, no. 14, pp. 3033-3035. https://doi.org/10.1021/cm901280w
Farha, Omar K. ; Spokoyny, Alexander M. ; Hauser, Brad G. ; Bae, Youn Sang ; Brown, Samantha E. ; Snurr, Randall Q. ; Mirkin, Chad A. ; Hupp, Joseph T. / Synthesis, properties, and gas separation studies of a robust diimide-based microporous organic polymer. In: Chemistry of Materials. 2009 ; Vol. 21, No. 14. pp. 3033-3035.
@article{00132b2ff6db4f29b58740d68ae3b5c8,
title = "Synthesis, properties, and gas separation studies of a robust diimide-based microporous organic polymer",
abstract = "The synthesis of a new porous organic polymer that features high surface area and pores of appropriate size and composition to capture CO 2 from mixtures with methane, was reported. The desired micro-and ultramicro-porosity was engendered by using a tetrahedral building block that is expected to produce a three-dimensional network. Single component adsorption isotherms for CO 2 and CH 4 were measured volumetrically for diimide subunits heated under a vacuum at 160°C. The selectivities for CO 2 CH 4 mixtures were calculated using ideal adsorbed solution theory (IAST). The first of these new materials, simply made from inexpensive precursors, shows outstanding thermal and chemical stability, and exceptional promise for CO 2 CH 4 separation.",
author = "Farha, {Omar K.} and Spokoyny, {Alexander M.} and Hauser, {Brad G.} and Bae, {Youn Sang} and Brown, {Samantha E.} and Snurr, {Randall Q.} and Mirkin, {Chad A.} and Hupp, {Joseph T}",
year = "2009",
month = "7",
day = "28",
doi = "10.1021/cm901280w",
language = "English",
volume = "21",
pages = "3033--3035",
journal = "Chemistry of Materials",
issn = "0897-4756",
publisher = "American Chemical Society",
number = "14",

}

TY - JOUR

T1 - Synthesis, properties, and gas separation studies of a robust diimide-based microporous organic polymer

AU - Farha, Omar K.

AU - Spokoyny, Alexander M.

AU - Hauser, Brad G.

AU - Bae, Youn Sang

AU - Brown, Samantha E.

AU - Snurr, Randall Q.

AU - Mirkin, Chad A.

AU - Hupp, Joseph T

PY - 2009/7/28

Y1 - 2009/7/28

N2 - The synthesis of a new porous organic polymer that features high surface area and pores of appropriate size and composition to capture CO 2 from mixtures with methane, was reported. The desired micro-and ultramicro-porosity was engendered by using a tetrahedral building block that is expected to produce a three-dimensional network. Single component adsorption isotherms for CO 2 and CH 4 were measured volumetrically for diimide subunits heated under a vacuum at 160°C. The selectivities for CO 2 CH 4 mixtures were calculated using ideal adsorbed solution theory (IAST). The first of these new materials, simply made from inexpensive precursors, shows outstanding thermal and chemical stability, and exceptional promise for CO 2 CH 4 separation.

AB - The synthesis of a new porous organic polymer that features high surface area and pores of appropriate size and composition to capture CO 2 from mixtures with methane, was reported. The desired micro-and ultramicro-porosity was engendered by using a tetrahedral building block that is expected to produce a three-dimensional network. Single component adsorption isotherms for CO 2 and CH 4 were measured volumetrically for diimide subunits heated under a vacuum at 160°C. The selectivities for CO 2 CH 4 mixtures were calculated using ideal adsorbed solution theory (IAST). The first of these new materials, simply made from inexpensive precursors, shows outstanding thermal and chemical stability, and exceptional promise for CO 2 CH 4 separation.

UR - http://www.scopus.com/inward/record.url?scp=67651087132&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67651087132&partnerID=8YFLogxK

U2 - 10.1021/cm901280w

DO - 10.1021/cm901280w

M3 - Article

VL - 21

SP - 3033

EP - 3035

JO - Chemistry of Materials

JF - Chemistry of Materials

SN - 0897-4756

IS - 14

ER -