Synthesis, structure, and properties of Li2Pb 2CuB4O10 with isolated [CuB4O 10]6- units

Hongyi Li, Shilie Pan, Hongping Wu, Jared P. Smit, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The copper borate Li2Pb2CuB4O10 has been synthesized in air by the standard solid-state reaction at temperature in the range 550-650 °C and the structure of Li2Pb 2CuB4O10 was determined by single-crystal X-ray diffraction. Li2Pb2CuB4O10 crystallizes in the monoclinic space group C2/c (no. 15) with a = 16.8419(12), b = 4.7895(4), c = 13.8976(10) , and β = 125.3620(10)°, V = 914.22(12) 3, and Z = 4, as determined by single-crystal X-ray diffraction. The Li2Pb2CuB4O10 structure exhibits isolated units of stoichiometry [CuB4O10]6- that are built from CuO4 distorted square planes and triangular BO3 groups. The IR spectroscopy and thermal analysis investigations of Li2Pb2CuB4O10 are also presented.

Original languageEnglish
Pages (from-to)3310-3313
Number of pages4
JournalJournal of Alloys and Compounds
Volume509
Issue number7
DOIs
Publication statusPublished - Feb 17 2011

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Single crystals
X ray diffraction
Borates
Solid state reactions
Stoichiometry
Thermoanalysis
Copper
Infrared spectroscopy
Air
Temperature

Keywords

  • Crystal structure
  • Oxide materials
  • Solid state reactions
  • X-ray diffraction

ASJC Scopus subject areas

  • Mechanical Engineering
  • Mechanics of Materials
  • Materials Chemistry
  • Metals and Alloys

Cite this

Synthesis, structure, and properties of Li2Pb 2CuB4O10 with isolated [CuB4O 10]6- units. / Li, Hongyi; Pan, Shilie; Wu, Hongping; Smit, Jared P.; Poeppelmeier, Kenneth R.

In: Journal of Alloys and Compounds, Vol. 509, No. 7, 17.02.2011, p. 3310-3313.

Research output: Contribution to journalArticle

Li, Hongyi ; Pan, Shilie ; Wu, Hongping ; Smit, Jared P. ; Poeppelmeier, Kenneth R. / Synthesis, structure, and properties of Li2Pb 2CuB4O10 with isolated [CuB4O 10]6- units. In: Journal of Alloys and Compounds. 2011 ; Vol. 509, No. 7. pp. 3310-3313.
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AU - Poeppelmeier, Kenneth R

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AB - The copper borate Li2Pb2CuB4O10 has been synthesized in air by the standard solid-state reaction at temperature in the range 550-650 °C and the structure of Li2Pb 2CuB4O10 was determined by single-crystal X-ray diffraction. Li2Pb2CuB4O10 crystallizes in the monoclinic space group C2/c (no. 15) with a = 16.8419(12), b = 4.7895(4), c = 13.8976(10) , and β = 125.3620(10)°, V = 914.22(12) 3, and Z = 4, as determined by single-crystal X-ray diffraction. The Li2Pb2CuB4O10 structure exhibits isolated units of stoichiometry [CuB4O10]6- that are built from CuO4 distorted square planes and triangular BO3 groups. The IR spectroscopy and thermal analysis investigations of Li2Pb2CuB4O10 are also presented.

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