Abstract
Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.
| Original language | English |
|---|---|
| Pages (from-to) | 916-924 |
| Number of pages | 9 |
| Journal | Materials Research Bulletin |
| Volume | 41 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - May 25 2006 |
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Keywords
- A. Oxide
- B. Crystal growth
- C. X-ray diffraction
- D. Crystal structure
- D. Magnetic properties
ASJC Scopus subject areas
- Ceramics and Composites
- Materials Chemistry
Cite this
Synthesis, structure and properties of Pb2CuB2O6. / Pan, Shilie; Smit, Jared P.; Marvel, Michael R.; Stern, Charlotte L.; Watkins, Byron; Poeppelmeier, Kenneth R.
In: Materials Research Bulletin, Vol. 41, No. 5, 25.05.2006, p. 916-924.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis, structure and properties of Pb2CuB2O6
AU - Pan, Shilie
AU - Smit, Jared P.
AU - Marvel, Michael R.
AU - Stern, Charlotte L.
AU - Watkins, Byron
AU - Poeppelmeier, Kenneth R
PY - 2006/5/25
Y1 - 2006/5/25
N2 - Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.
AB - Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.
KW - A. Oxide
KW - B. Crystal growth
KW - C. X-ray diffraction
KW - D. Crystal structure
KW - D. Magnetic properties
UR - http://www.scopus.com/inward/record.url?scp=33747618729&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33747618729&partnerID=8YFLogxK
U2 - 10.1016/j.materresbull.2005.12.012
DO - 10.1016/j.materresbull.2005.12.012
M3 - Article
AN - SCOPUS:33747618729
VL - 41
SP - 916
EP - 924
JO - Materials Research Bulletin
JF - Materials Research Bulletin
SN - 0025-5408
IS - 5
ER -