TY - JOUR
T1 - Synthesis, structure and properties of Pb2CuB2O6
AU - Pan, Shilie
AU - Smit, Jared P.
AU - Marvel, Michael R.
AU - Stern, Charlotte L.
AU - Watkins, Byron
AU - Poeppelmeier, Kenneth R.
N1 - Funding Information:
We gratefully acknowledge the support from the National Science Foundation (Solid State Chemistry Award No. DMR-0312136), the EMSI program of the National Science Foundation at the Northwestern University Institute for Environmental Catalysis (Grant No. 9810378), and the Department of Energy, BES-Chemical Sciences, Geosciences, and Biosciences Division under grant No. DE-FG0203ER15457 for support of this work, and the use of the Central Facilities supported by the MRSEC program of the National Science Foundation (DMR-0076097) at the Materials Research Center of Northwestern University.
PY - 2006/5/25
Y1 - 2006/5/25
N2 - Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.
AB - Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.
KW - A. Oxide
KW - B. Crystal growth
KW - C. X-ray diffraction
KW - D. Crystal structure
KW - D. Magnetic properties
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U2 - 10.1016/j.materresbull.2005.12.012
DO - 10.1016/j.materresbull.2005.12.012
M3 - Article
AN - SCOPUS:33747618729
VL - 41
SP - 916
EP - 924
JO - Materials Research Bulletin
JF - Materials Research Bulletin
SN - 0025-5408
IS - 5
ER -