Synthesis, structure and properties of Pb2CuB2O6

Shilie Pan; Jared P. Smit; Michael R. Marvel; Charlotte L. Stern; Byron Watkins; Kenneth R. Poeppelmeier

doi:10.1016/j.materresbull.2005.12.012

Synthesis, structure and properties of Pb₂CuB₂O₆

Shilie Pan, Jared P. Smit, Michael R. Marvel, Charlotte L. Stern, Byron Watkins, Kenneth R. Poeppelmeier

Northwestern University

Research output: Contribution to journal › Article

22 Citations (Scopus)

Abstract

Single crystals of Pb₂CuB₂O₆ were grown from a PbO/CuO/B₂O₃ flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P2₁/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R₁ = 0.0217, wR₂ = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO₄ and triangular planar BO₃ groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.

Original language	English
Pages (from-to)	916-924
Number of pages	9
Journal	Materials Research Bulletin
Volume	41
Issue number	5
DOIs	https://doi.org/10.1016/j.materresbull.2005.12.012
Publication status	Published - May 25 2006

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Keywords

A. Oxide
B. Crystal growth
C. X-ray diffraction
D. Crystal structure
D. Magnetic properties

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Cite this

Pan, S., Smit, J. P., Marvel, M. R., Stern, C. L., Watkins, B., & Poeppelmeier, K. R. (2006). Synthesis, structure and properties of Pb₂CuB₂O₆. Materials Research Bulletin, 41(5), 916-924. https://doi.org/10.1016/j.materresbull.2005.12.012

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title = "Synthesis, structure and properties of Pb2CuB2O6",

abstract = "Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) {\AA}, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.",

keywords = "A. Oxide, B. Crystal growth, C. X-ray diffraction, D. Crystal structure, D. Magnetic properties",

author = "Shilie Pan and Smit, {Jared P.} and Marvel, {Michael R.} and Stern, {Charlotte L.} and Byron Watkins and Poeppelmeier, {Kenneth R.}",

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AU - Pan, Shilie

AU - Smit, Jared P.

AU - Marvel, Michael R.

AU - Stern, Charlotte L.

AU - Watkins, Byron

AU - Poeppelmeier, Kenneth R.

PY - 2006/5/25

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N2 - Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.

AB - Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.

KW - A. Oxide

KW - B. Crystal growth

KW - C. X-ray diffraction

KW - D. Crystal structure

KW - D. Magnetic properties

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Access to Document

10.1016/j.materresbull.2005.12.012