Synthesis, structure and properties of Pb2CuB2O6

Shilie Pan, Jared P. Smit, Michael R. Marvel, Charlotte L. Stern, Byron Watkins, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.

Original languageEnglish
Pages (from-to)916-924
Number of pages9
JournalMaterials Research Bulletin
Volume41
Issue number5
DOIs
Publication statusPublished - May 25 2006

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Vibrational spectroscopy
Differential thermal analysis
Single crystals
Fluxes
synthesis
Chemical analysis
quantitative analysis
thermal analysis
single crystals
cells
spectroscopy
boron oxide

Keywords

  • A. Oxide
  • B. Crystal growth
  • C. X-ray diffraction
  • D. Crystal structure
  • D. Magnetic properties

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

Cite this

Synthesis, structure and properties of Pb2CuB2O6. / Pan, Shilie; Smit, Jared P.; Marvel, Michael R.; Stern, Charlotte L.; Watkins, Byron; Poeppelmeier, Kenneth R.

In: Materials Research Bulletin, Vol. 41, No. 5, 25.05.2006, p. 916-924.

Research output: Contribution to journalArticle

Pan, Shilie ; Smit, Jared P. ; Marvel, Michael R. ; Stern, Charlotte L. ; Watkins, Byron ; Poeppelmeier, Kenneth R. / Synthesis, structure and properties of Pb2CuB2O6. In: Materials Research Bulletin. 2006 ; Vol. 41, No. 5. pp. 916-924.
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