Synthesis, structure and properties of Pb2CuB2O6

Shilie Pan; Jared P. Smit; Michael R. Marvel; Charlotte L. Stern; Byron Watkins; Kenneth R. Poeppelmeier

doi:10.1016/j.materresbull.2005.12.012

Synthesis, structure and properties of Pb₂CuB₂O₆

Shilie Pan, Jared P. Smit, Michael R. Marvel, Charlotte L. Stern, Byron Watkins, Kenneth R. Poeppelmeier

Northwestern University

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Single crystals of Pb₂CuB₂O₆ were grown from a PbO/CuO/B₂O₃ flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P2₁/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R₁ = 0.0217, wR₂ = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO₄ and triangular planar BO₃ groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.

Original language	English
Pages (from-to)	916-924
Number of pages	9
Journal	Materials Research Bulletin
Volume	41
Issue number	5
DOIs	https://doi.org/10.1016/j.materresbull.2005.12.012
Publication status	Published - May 25 2006

Keywords

A. Oxide
B. Crystal growth
C. X-ray diffraction
D. Crystal structure
D. Magnetic properties

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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title = "Synthesis, structure and properties of Pb2CuB2O6",

abstract = "Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) {\AA}, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.",

keywords = "A. Oxide, B. Crystal growth, C. X-ray diffraction, D. Crystal structure, D. Magnetic properties",

author = "Shilie Pan and Smit, {Jared P.} and Marvel, {Michael R.} and Stern, {Charlotte L.} and Byron Watkins and Poeppelmeier, {Kenneth R.}",

note = "Funding Information: We gratefully acknowledge the support from the National Science Foundation (Solid State Chemistry Award No. DMR-0312136), the EMSI program of the National Science Foundation at the Northwestern University Institute for Environmental Catalysis (Grant No. 9810378), and the Department of Energy, BES-Chemical Sciences, Geosciences, and Biosciences Division under grant No. DE-FG0203ER15457 for support of this work, and the use of the Central Facilities supported by the MRSEC program of the National Science Foundation (DMR-0076097) at the Materials Research Center of Northwestern University. ",

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AU - Pan, Shilie

AU - Smit, Jared P.

AU - Marvel, Michael R.

AU - Stern, Charlotte L.

AU - Watkins, Byron

AU - Poeppelmeier, Kenneth R.

N1 - Funding Information: We gratefully acknowledge the support from the National Science Foundation (Solid State Chemistry Award No. DMR-0312136), the EMSI program of the National Science Foundation at the Northwestern University Institute for Environmental Catalysis (Grant No. 9810378), and the Department of Energy, BES-Chemical Sciences, Geosciences, and Biosciences Division under grant No. DE-FG0203ER15457 for support of this work, and the use of the Central Facilities supported by the MRSEC program of the National Science Foundation (DMR-0076097) at the Materials Research Center of Northwestern University.

PY - 2006/5/25

Y1 - 2006/5/25

N2 - Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.

AB - Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) Å, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, wR2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.

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KW - D. Magnetic properties

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