Abstract
Two tellurostannates, [Mn(en)3]2(Sn2Te6) (I) and [Zn(en)3]2(Sn2Te6) (II), have been synthesized via low temperature solvothermal reactions. Both are Zintl compounds and contain (Sn2Te6)4- dimeric units and metal coordination complex cations. Compounds I and II were prepared at temperatures between 170 and 180°C using ethylenediamine as solvent. [Mn(en)3]2(Sn2Te6) crystallizes in orthorhombic crystal system, space group Pbca (No. 61), with a = 15.797(2), b = 12.640(2), c = 20.175(2) Å, Z = 4. [Zn(en)3]2(Sn2Te6) belongs to monoclinic system, space group P2I/n (No. 14) with a = 9.048(2), b = 22.300(6), c = 9.360(3) Å, Z = 4. Temperature dependent susceptibility measurements and isothermal magnetization on I show a typical paramagnetic behavior and a magnetic moment of μ = 3.56 μB was calculated for this compound.
| Original language | English |
|---|---|
| Pages (from-to) | 310-315 |
| Number of pages | 6 |
| Journal | Inorganica Chimica Acta |
| Volume | 273 |
| Issue number | 1-2 |
| Publication status | Published - May 15 1998 |
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Keywords
- Crystal structures
- Magnetic properties
- Manganese complexes
- Telluride complexes
- Zinc complexes
ASJC Scopus subject areas
- Biochemistry
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Synthesis, structure characterization and magnetic properties of tellurostannates [M(en)3]2(Sn2Te6) (M = Mn, Zn). / Li, Jing; Chen, Zhen; Emge, Thomas J.; Yuen, Tan; Proserpio, Davide M.
In: Inorganica Chimica Acta, Vol. 273, No. 1-2, 15.05.1998, p. 310-315.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Synthesis, structure characterization and magnetic properties of tellurostannates [M(en)3]2(Sn2Te6) (M = Mn, Zn)
AU - Li, Jing
AU - Chen, Zhen
AU - Emge, Thomas J.
AU - Yuen, Tan
AU - Proserpio, Davide M.
PY - 1998/5/15
Y1 - 1998/5/15
N2 - Two tellurostannates, [Mn(en)3]2(Sn2Te6) (I) and [Zn(en)3]2(Sn2Te6) (II), have been synthesized via low temperature solvothermal reactions. Both are Zintl compounds and contain (Sn2Te6)4- dimeric units and metal coordination complex cations. Compounds I and II were prepared at temperatures between 170 and 180°C using ethylenediamine as solvent. [Mn(en)3]2(Sn2Te6) crystallizes in orthorhombic crystal system, space group Pbca (No. 61), with a = 15.797(2), b = 12.640(2), c = 20.175(2) Å, Z = 4. [Zn(en)3]2(Sn2Te6) belongs to monoclinic system, space group P2I/n (No. 14) with a = 9.048(2), b = 22.300(6), c = 9.360(3) Å, Z = 4. Temperature dependent susceptibility measurements and isothermal magnetization on I show a typical paramagnetic behavior and a magnetic moment of μ = 3.56 μB was calculated for this compound.
AB - Two tellurostannates, [Mn(en)3]2(Sn2Te6) (I) and [Zn(en)3]2(Sn2Te6) (II), have been synthesized via low temperature solvothermal reactions. Both are Zintl compounds and contain (Sn2Te6)4- dimeric units and metal coordination complex cations. Compounds I and II were prepared at temperatures between 170 and 180°C using ethylenediamine as solvent. [Mn(en)3]2(Sn2Te6) crystallizes in orthorhombic crystal system, space group Pbca (No. 61), with a = 15.797(2), b = 12.640(2), c = 20.175(2) Å, Z = 4. [Zn(en)3]2(Sn2Te6) belongs to monoclinic system, space group P2I/n (No. 14) with a = 9.048(2), b = 22.300(6), c = 9.360(3) Å, Z = 4. Temperature dependent susceptibility measurements and isothermal magnetization on I show a typical paramagnetic behavior and a magnetic moment of μ = 3.56 μB was calculated for this compound.
KW - Crystal structures
KW - Magnetic properties
KW - Manganese complexes
KW - Telluride complexes
KW - Zinc complexes
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UR - http://www.scopus.com/inward/citedby.url?scp=0007787962&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0007787962
VL - 273
SP - 310
EP - 315
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
IS - 1-2
ER -