Synthesis, structure characterization and magnetic properties of tellurostannates [M(en)3]2(Sn2Te6) (M = Mn, Zn)

Jing Li; Zhen Chen; Thomas J. Emge; Tan Yuen; Davide M. Proserpio

Synthesis, structure characterization and magnetic properties of tellurostannates [M(en)₃]₂(Sn₂Te₆) (M = Mn, Zn)

Jing Li, Zhen Chen, Thomas J. Emge, Tan Yuen, Davide M. Proserpio

Rutgers University

Research output: Contribution to journal › Article

68 Citations (Scopus)

Abstract

Two tellurostannates, [Mn(en)₃]₂(Sn₂Te₆) (I) and [Zn(en)₃]₂(Sn₂Te₆) (II), have been synthesized via low temperature solvothermal reactions. Both are Zintl compounds and contain (Sn₂Te₆)^4- dimeric units and metal coordination complex cations. Compounds I and II were prepared at temperatures between 170 and 180°C using ethylenediamine as solvent. [Mn(en)₃]₂(Sn₂Te₆) crystallizes in orthorhombic crystal system, space group Pbca (No. 61), with a = 15.797(2), b = 12.640(2), c = 20.175(2) Å, Z = 4. [Zn(en)₃]₂(Sn₂Te₆) belongs to monoclinic system, space group P2_I/n (No. 14) with a = 9.048(2), b = 22.300(6), c = 9.360(3) Å, Z = 4. Temperature dependent susceptibility measurements and isothermal magnetization on I show a typical paramagnetic behavior and a magnetic moment of μ = 3.56 μ_B was calculated for this compound.

Original language	English
Pages (from-to)	310-315
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	273
Issue number	1-2
Publication status	Published - May 15 1998

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Keywords

Crystal structures
Magnetic properties
Manganese complexes
Telluride complexes
Zinc complexes

ASJC Scopus subject areas

Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Chemistry

Cite this

Li, J., Chen, Z., Emge, T. J., Yuen, T., & Proserpio, D. M. (1998). Synthesis, structure characterization and magnetic properties of tellurostannates [M(en)₃]₂(Sn₂Te₆) (M = Mn, Zn). Inorganica Chimica Acta, 273(1-2), 310-315.

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abstract = "Two tellurostannates, [Mn(en)3]2(Sn2Te6) (I) and [Zn(en)3]2(Sn2Te6) (II), have been synthesized via low temperature solvothermal reactions. Both are Zintl compounds and contain (Sn2Te6)4- dimeric units and metal coordination complex cations. Compounds I and II were prepared at temperatures between 170 and 180°C using ethylenediamine as solvent. [Mn(en)3]2(Sn2Te6) crystallizes in orthorhombic crystal system, space group Pbca (No. 61), with a = 15.797(2), b = 12.640(2), c = 20.175(2) {\AA}, Z = 4. [Zn(en)3]2(Sn2Te6) belongs to monoclinic system, space group P2I/n (No. 14) with a = 9.048(2), b = 22.300(6), c = 9.360(3) {\AA}, Z = 4. Temperature dependent susceptibility measurements and isothermal magnetization on I show a typical paramagnetic behavior and a magnetic moment of μ = 3.56 μB was calculated for this compound.",

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