Synthesis, structure characterization and magnetic properties of tellurostannates [M(en)3]2(Sn2Te6) (M = Mn, Zn)

Jing Li; Zhen Chen; Thomas J. Emge; Tan Yuen; Davide M. Proserpio

doi:10.1016/s0020-1693(97)06035-0

Synthesis, structure characterization and magnetic properties of tellurostannates [M(en)₃]₂(Sn₂Te₆) (M = Mn, Zn)

Jing Li, Zhen Chen, Thomas J. Emge, Tan Yuen, Davide M. Proserpio

Rutgers University

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

Two tellurostannates, [Mn(en)₃]₂(Sn₂Te₆) (I) and [Zn(en)₃]₂(Sn₂Te₆) (II), have been synthesized via low temperature solvothermal reactions. Both are Zintl compounds and contain (Sn₂Te₆)^4- dimeric units and metal coordination complex cations. Compounds I and II were prepared at temperatures between 170 and 180°C using ethylenediamine as solvent. [Mn(en)₃]₂(Sn₂Te₆) crystallizes in orthorhombic crystal system, space group Pbca (No. 61), with a = 15.797(2), b = 12.640(2), c = 20.175(2) Å, Z = 4. [Zn(en)₃]₂(Sn₂Te₆) belongs to monoclinic system, space group P2_I/n (No. 14) with a = 9.048(2), b = 22.300(6), c = 9.360(3) Å, Z = 4. Temperature dependent susceptibility measurements and isothermal magnetization on I show a typical paramagnetic behavior and a magnetic moment of μ = 3.56 μ_B was calculated for this compound.

Original language	English
Pages (from-to)	310-315
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	273
Issue number	1-2
DOIs	https://doi.org/10.1016/s0020-1693(97)06035-0
Publication status	Published - May 15 1998

Keywords

Crystal structures
Magnetic properties
Manganese complexes
Telluride complexes
Zinc complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/s0020-1693(97)06035-0

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title = "Synthesis, structure characterization and magnetic properties of tellurostannates [M(en)3]2(Sn2Te6) (M = Mn, Zn)",

abstract = "Two tellurostannates, [Mn(en)3]2(Sn2Te6) (I) and [Zn(en)3]2(Sn2Te6) (II), have been synthesized via low temperature solvothermal reactions. Both are Zintl compounds and contain (Sn2Te6)4- dimeric units and metal coordination complex cations. Compounds I and II were prepared at temperatures between 170 and 180°C using ethylenediamine as solvent. [Mn(en)3]2(Sn2Te6) crystallizes in orthorhombic crystal system, space group Pbca (No. 61), with a = 15.797(2), b = 12.640(2), c = 20.175(2) {\AA}, Z = 4. [Zn(en)3]2(Sn2Te6) belongs to monoclinic system, space group P2I/n (No. 14) with a = 9.048(2), b = 22.300(6), c = 9.360(3) {\AA}, Z = 4. Temperature dependent susceptibility measurements and isothermal magnetization on I show a typical paramagnetic behavior and a magnetic moment of μ = 3.56 μB was calculated for this compound.",

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T1 - Synthesis, structure characterization and magnetic properties of tellurostannates [M(en)3]2(Sn2Te6) (M = Mn, Zn)

AU - Li, Jing

AU - Chen, Zhen

AU - Emge, Thomas J.

AU - Yuen, Tan

AU - Proserpio, Davide M.

PY - 1998/5/15

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N2 - Two tellurostannates, [Mn(en)3]2(Sn2Te6) (I) and [Zn(en)3]2(Sn2Te6) (II), have been synthesized via low temperature solvothermal reactions. Both are Zintl compounds and contain (Sn2Te6)4- dimeric units and metal coordination complex cations. Compounds I and II were prepared at temperatures between 170 and 180°C using ethylenediamine as solvent. [Mn(en)3]2(Sn2Te6) crystallizes in orthorhombic crystal system, space group Pbca (No. 61), with a = 15.797(2), b = 12.640(2), c = 20.175(2) Å, Z = 4. [Zn(en)3]2(Sn2Te6) belongs to monoclinic system, space group P2I/n (No. 14) with a = 9.048(2), b = 22.300(6), c = 9.360(3) Å, Z = 4. Temperature dependent susceptibility measurements and isothermal magnetization on I show a typical paramagnetic behavior and a magnetic moment of μ = 3.56 μB was calculated for this compound.

AB - Two tellurostannates, [Mn(en)3]2(Sn2Te6) (I) and [Zn(en)3]2(Sn2Te6) (II), have been synthesized via low temperature solvothermal reactions. Both are Zintl compounds and contain (Sn2Te6)4- dimeric units and metal coordination complex cations. Compounds I and II were prepared at temperatures between 170 and 180°C using ethylenediamine as solvent. [Mn(en)3]2(Sn2Te6) crystallizes in orthorhombic crystal system, space group Pbca (No. 61), with a = 15.797(2), b = 12.640(2), c = 20.175(2) Å, Z = 4. [Zn(en)3]2(Sn2Te6) belongs to monoclinic system, space group P2I/n (No. 14) with a = 9.048(2), b = 22.300(6), c = 9.360(3) Å, Z = 4. Temperature dependent susceptibility measurements and isothermal magnetization on I show a typical paramagnetic behavior and a magnetic moment of μ = 3.56 μB was calculated for this compound.

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KW - Zinc complexes

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