Synthetic Access to Atomically Dispersed Metals in Metal-Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach

Rachel C. Klet, Timothy C. Wang, Laura E. Fernandez, Donald G. Truhlar, Joseph T Hupp, Omar K. Farha

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

The combination (AIM-ME) of atomic layer deposition in metal-organic frameworks (MOFs) and metal exchange (ME) is introduced as a technique to install dispersed metal atoms into the mesoporous MOF, NU-1000. Zn-AIM, which contains four Zn atoms per Zr6 node, has been synthesized through AIM and further characterized through density functional calculations to provide insight into the possible structure. Zn-AIM was then subjected to modification via transmetalation to yield uniform porous materials that present nonstructural Cu, Co, or Ni atoms. (Figure Presented).

Original languageEnglish
Pages (from-to)1213-1219
Number of pages7
JournalChemistry of Materials
Volume28
Issue number4
DOIs
Publication statusPublished - Feb 23 2016

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Atomic layer deposition
Metals
Atoms
Density functional theory
Porous materials

ASJC Scopus subject areas

  • Materials Chemistry
  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Synthetic Access to Atomically Dispersed Metals in Metal-Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach. / Klet, Rachel C.; Wang, Timothy C.; Fernandez, Laura E.; Truhlar, Donald G.; Hupp, Joseph T; Farha, Omar K.

In: Chemistry of Materials, Vol. 28, No. 4, 23.02.2016, p. 1213-1219.

Research output: Contribution to journalArticle

Klet, Rachel C. ; Wang, Timothy C. ; Fernandez, Laura E. ; Truhlar, Donald G. ; Hupp, Joseph T ; Farha, Omar K. / Synthetic Access to Atomically Dispersed Metals in Metal-Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach. In: Chemistry of Materials. 2016 ; Vol. 28, No. 4. pp. 1213-1219.
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