Abstract
The combination (AIM-ME) of atomic layer deposition in metal-organic frameworks (MOFs) and metal exchange (ME) is introduced as a technique to install dispersed metal atoms into the mesoporous MOF, NU-1000. Zn-AIM, which contains four Zn atoms per Zr6 node, has been synthesized through AIM and further characterized through density functional calculations to provide insight into the possible structure. Zn-AIM was then subjected to modification via transmetalation to yield uniform porous materials that present nonstructural Cu, Co, or Ni atoms. (Figure Presented).
| Original language | English |
|---|---|
| Pages (from-to) | 1213-1219 |
| Number of pages | 7 |
| Journal | Chemistry of Materials |
| Volume | 28 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Feb 23 2016 |
ASJC Scopus subject areas
- Materials Chemistry
- Chemical Engineering(all)
- Chemistry(all)
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Klet, R. C., Wang, T. C., Fernandez, L. E., Truhlar, D. G., Hupp, J. T., & Farha, O. K. (2016). Synthetic Access to Atomically Dispersed Metals in Metal-Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach. Chemistry of Materials, 28(4), 1213-1219. https://doi.org/10.1021/acs.chemmater.5b04887