Abstract
This paper focuses on homogeneous catalysts for the oxidation of water. It provides an overview of the photosynthetic water-oxidizing complex (WOC) and its functionality, followed by analysis of the thermodynamic and kinetic constraints for water-oxidation that have to be overcome by any catalyst. Since manganese is the metal that performs this reaction in the WOC, manganese catalysts are discussed, followed by ruthenium. Finally, the principles of reactivity learned from theory and existing models that will guide toward synthesis of better catalysts in the future are summarized.
| Original language | English |
|---|---|
| Pages (from-to) | 1-24 |
| Number of pages | 24 |
| Journal | Chemical Reviews |
| Volume | 97 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 1997 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Synthetic water-oxidation catalysts for artificial photosynthetic water oxidation. / Ruttinger, Wolfgang; Dismukes, G Charles.
In: Chemical Reviews, Vol. 97, No. 1, 01.1997, p. 1-24.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthetic water-oxidation catalysts for artificial photosynthetic water oxidation
AU - Ruttinger, Wolfgang
AU - Dismukes, G Charles
PY - 1997/1
Y1 - 1997/1
N2 - This paper focuses on homogeneous catalysts for the oxidation of water. It provides an overview of the photosynthetic water-oxidizing complex (WOC) and its functionality, followed by analysis of the thermodynamic and kinetic constraints for water-oxidation that have to be overcome by any catalyst. Since manganese is the metal that performs this reaction in the WOC, manganese catalysts are discussed, followed by ruthenium. Finally, the principles of reactivity learned from theory and existing models that will guide toward synthesis of better catalysts in the future are summarized.
AB - This paper focuses on homogeneous catalysts for the oxidation of water. It provides an overview of the photosynthetic water-oxidizing complex (WOC) and its functionality, followed by analysis of the thermodynamic and kinetic constraints for water-oxidation that have to be overcome by any catalyst. Since manganese is the metal that performs this reaction in the WOC, manganese catalysts are discussed, followed by ruthenium. Finally, the principles of reactivity learned from theory and existing models that will guide toward synthesis of better catalysts in the future are summarized.
UR - http://www.scopus.com/inward/record.url?scp=0030673290&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0030673290&partnerID=8YFLogxK
U2 - 10.1021/cr950201z
DO - 10.1021/cr950201z
M3 - Article
AN - SCOPUS:0030673290
VL - 97
SP - 1
EP - 24
JO - Chemical Reviews
JF - Chemical Reviews
SN - 0009-2665
IS - 1
ER -