Abstract
A convenient and general method for the preparation of (h5-C5H5)(L)Cu compounds is described and illustrated for compounds with L = (C2H5)3P, (C4H9)4P, (C6H5)3P, (CH3O)3P, and CH3NC. The method involves reaction of the appropriate (LCuI)4 or (LCuBr)4 compound with C5H5Tl. The compounds have all been characterized by analyses, pmr, infrared and mass spectra, and, for L = (C6H5)3P and (C2H5)3P, by X-ray diffraction as pentahaptocyclopentadienyl compounds. The compound (h5-C5H5)(CO)Cu has also been prepared by reaction of CuCl, C5H5Tl, and CO in pentane at 0°. It has a very high CO stretching frequency (2093 cm-1) and decomposes rapidly at room temperature.
| Original language | English |
|---|---|
| Pages (from-to) | 5114-5117 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 92 |
| Issue number | 17 |
| Publication status | Published - 1970 |
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Systematic preparation and characterization of pentahaptocyclopentadienylcopper(I) compounds. / Cotton, F. A.; Marks, Tobin J.
In: Journal of the American Chemical Society, Vol. 92, No. 17, 1970, p. 5114-5117.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Systematic preparation and characterization of pentahaptocyclopentadienylcopper(I) compounds
AU - Cotton, F. A.
AU - Marks, Tobin J
PY - 1970
Y1 - 1970
N2 - A convenient and general method for the preparation of (h5-C5H5)(L)Cu compounds is described and illustrated for compounds with L = (C2H5)3P, (C4H9)4P, (C6H5)3P, (CH3O)3P, and CH3NC. The method involves reaction of the appropriate (LCuI)4 or (LCuBr)4 compound with C5H5Tl. The compounds have all been characterized by analyses, pmr, infrared and mass spectra, and, for L = (C6H5)3P and (C2H5)3P, by X-ray diffraction as pentahaptocyclopentadienyl compounds. The compound (h5-C5H5)(CO)Cu has also been prepared by reaction of CuCl, C5H5Tl, and CO in pentane at 0°. It has a very high CO stretching frequency (2093 cm-1) and decomposes rapidly at room temperature.
AB - A convenient and general method for the preparation of (h5-C5H5)(L)Cu compounds is described and illustrated for compounds with L = (C2H5)3P, (C4H9)4P, (C6H5)3P, (CH3O)3P, and CH3NC. The method involves reaction of the appropriate (LCuI)4 or (LCuBr)4 compound with C5H5Tl. The compounds have all been characterized by analyses, pmr, infrared and mass spectra, and, for L = (C6H5)3P and (C2H5)3P, by X-ray diffraction as pentahaptocyclopentadienyl compounds. The compound (h5-C5H5)(CO)Cu has also been prepared by reaction of CuCl, C5H5Tl, and CO in pentane at 0°. It has a very high CO stretching frequency (2093 cm-1) and decomposes rapidly at room temperature.
UR - http://www.scopus.com/inward/record.url?scp=0001697634&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0001697634&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0001697634
VL - 92
SP - 5114
EP - 5117
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 17
ER -