Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate

Olena Branytska; Linda J.W. Shimon; Ronny Neumann

doi:10.1039/b710100g

Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate

Olena Branytska, Linda J.W. Shimon, Ronny Neumann

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article

16 Citations (Scopus)

Abstract

Together with a strongly oxidizing polyoxometalate, H₅PV ₂Mo₁₀O₄₀, Pt^II(N-(2,6- diisopropylphenyl)pyrazin-2-ylmethanimine)Cl₂ forms a combined catalyst that was active in the tandem pinacol coupling-rearrangement of aryl aldehydes to give mostly the corresponding diarylacetaldehyde in high yields using molecular hydrogen as the reducing agent.

Original language	English
Pages (from-to)	3957-3959
Number of pages	3
Journal	Chemical Communications
Issue number	38
DOIs	https://doi.org/10.1039/b710100g
Publication status	Published - Dec 1 2007

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Branytska, O., Shimon, L. J. W., & Neumann, R. (2007). Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate. Chemical Communications, (38), 3957-3959. https://doi.org/10.1039/b710100g

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Access to Document

10.1039/b710100g