Abstract
Technetium dichloride has been discovered. It was synthesized from the elements and characterized by several physical techniques, including single crystal X-ray diffraction. In the solid state, technetium dichloride exhibits a new structure type consisting of infinite chains of face sharing [Tc 2Cl8] rectangular prisms that are packed in a commensurate supercell. The metal-metal separation in the prisms is 2.127(2) Å, a distance consistent with the presence of a Tc=Tc triple bond that is also supported by electronic structure calculations.
| Original language | English |
|---|---|
| Pages (from-to) | 8814-8817 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 133 |
| Issue number | 23 |
| DOIs | |
| Publication status | Published - Jun 15 2011 |
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ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Technetium dichloride : A new binary halide containing metal-metal multiple bonds. / Poineau, Frederic; Malliakas, Christos D.; Weck, Philippe F.; Scott, Brian L.; Johnstone, Erik V.; Forster, Paul M.; Kim, Eunja; Kanatzidis, Mercouri G; Czerwinski, Kenneth R.; Sattelberger, Alfred P.
In: Journal of the American Chemical Society, Vol. 133, No. 23, 15.06.2011, p. 8814-8817.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Technetium dichloride
T2 - A new binary halide containing metal-metal multiple bonds
AU - Poineau, Frederic
AU - Malliakas, Christos D.
AU - Weck, Philippe F.
AU - Scott, Brian L.
AU - Johnstone, Erik V.
AU - Forster, Paul M.
AU - Kim, Eunja
AU - Kanatzidis, Mercouri G
AU - Czerwinski, Kenneth R.
AU - Sattelberger, Alfred P.
PY - 2011/6/15
Y1 - 2011/6/15
N2 - Technetium dichloride has been discovered. It was synthesized from the elements and characterized by several physical techniques, including single crystal X-ray diffraction. In the solid state, technetium dichloride exhibits a new structure type consisting of infinite chains of face sharing [Tc 2Cl8] rectangular prisms that are packed in a commensurate supercell. The metal-metal separation in the prisms is 2.127(2) Å, a distance consistent with the presence of a Tc=Tc triple bond that is also supported by electronic structure calculations.
AB - Technetium dichloride has been discovered. It was synthesized from the elements and characterized by several physical techniques, including single crystal X-ray diffraction. In the solid state, technetium dichloride exhibits a new structure type consisting of infinite chains of face sharing [Tc 2Cl8] rectangular prisms that are packed in a commensurate supercell. The metal-metal separation in the prisms is 2.127(2) Å, a distance consistent with the presence of a Tc=Tc triple bond that is also supported by electronic structure calculations.
UR - http://www.scopus.com/inward/record.url?scp=79958774804&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=79958774804&partnerID=8YFLogxK
U2 - 10.1021/ja201788m
DO - 10.1021/ja201788m
M3 - Article
C2 - 21574580
AN - SCOPUS:79958774804
VL - 133
SP - 8814
EP - 8817
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 23
ER -