Temperature-dependent excitonic decay and multiple states in single-wall carbon nanotubes

Wyatt K. Metzger, Timothy J. McDonald, Chaiwat Engtrakul, Jeffrey L. Blackburn, Gregory D. Scholes, Garry Rumbles, Michael J. Heben

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

We have performed steady-state photoluminescence, time-correlated single photon counting, and Raman spectroscopy measurements on single-wall carbon nanotubes from 4 to 293 K. We observe novel photoluminescence spectra that cannot be attributed to vibronic transitions and verify the existence and energy levels of weakly emissive excitonic states. By combining photoluminescence intensity and lifetime data, we determine how nonradiative and radiative excitonic decay rates change as a function of temperature and contrast this with theoretical predictions. The results suggest that recombination kinetics are influenced by multiple excitonic states, including a dark lower state.

Original languageEnglish
Pages (from-to)3601-3606
Number of pages6
JournalJournal of Physical Chemistry C
Volume111
Issue number9
DOIs
Publication statusPublished - Mar 8 2007

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

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    Metzger, W. K., McDonald, T. J., Engtrakul, C., Blackburn, J. L., Scholes, G. D., Rumbles, G., & Heben, M. J. (2007). Temperature-dependent excitonic decay and multiple states in single-wall carbon nanotubes. Journal of Physical Chemistry C, 111(9), 3601-3606. https://doi.org/10.1021/jp066725s