Temperature driven reactant solubilization synthesis of BiCuOSe

Evan S. Stampler, William C. Sheets, Mariana I. Bertoni, Wilfrid Prellier, Thomas O Mason, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Phase-pure BiCuOSe, which is isostructural to the layered p-type transparent conductor LaCuOS, has been synthesized in high yield by a single-step hydrothermal reaction at low temperature (250°C) and pressure (2O3 and Cu2O and stabilize monovalent copper and low enough to impede the oxidation of dianionic selenium. BiCuOSe exhibits a relatively high electrical conductivity (σ ≈ 3.3 S cm-1) and a reduced band gap (Eg = 0.75 eV), which compare favorably with the optoelectronic properties of BiCuOS and the cerium-based oxysulfides, CeAgOS and CeCuOS.

Original languageEnglish
Pages (from-to)10009-10016
Number of pages8
JournalInorganic Chemistry
Volume47
Issue number21
DOIs
Publication statusPublished - Nov 3 2008

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Cerium
Selenium
selenium
cerium
Optoelectronic devices
Copper
Energy gap
low pressure
conductors
copper
Oxidation
oxidation
electrical resistivity
synthesis
Temperature
temperature
Electric Conductivity

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Temperature driven reactant solubilization synthesis of BiCuOSe. / Stampler, Evan S.; Sheets, William C.; Bertoni, Mariana I.; Prellier, Wilfrid; Mason, Thomas O; Poeppelmeier, Kenneth R.

In: Inorganic Chemistry, Vol. 47, No. 21, 03.11.2008, p. 10009-10016.

Research output: Contribution to journalArticle

Stampler, ES, Sheets, WC, Bertoni, MI, Prellier, W, Mason, TO & Poeppelmeier, KR 2008, 'Temperature driven reactant solubilization synthesis of BiCuOSe', Inorganic Chemistry, vol. 47, no. 21, pp. 10009-10016. https://doi.org/10.1021/ic801267m
Stampler, Evan S. ; Sheets, William C. ; Bertoni, Mariana I. ; Prellier, Wilfrid ; Mason, Thomas O ; Poeppelmeier, Kenneth R. / Temperature driven reactant solubilization synthesis of BiCuOSe. In: Inorganic Chemistry. 2008 ; Vol. 47, No. 21. pp. 10009-10016.
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