Abstract
The title complex, [Ni4(C36H40N 2O2)2(OH)4(C3H 9OP)2(H2O)4]·2C 4H10O·2C3H9OP·2H 2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octa-hedral geometry.
| Original language | English |
|---|---|
| Pages (from-to) | m257 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 66 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Mar 19 2010 |
Keywords
- Data-to-parameter ratio = 15.0
- Hatom completeness 98%
- Mean σ(C-C) = 0.005 Å
- R factor = 0.046
- Single-crystal X-ray study
- T = 100 K
- WR factor = 0.162
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
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Delferro, M., Weberski, M. P., Rodriguez, B. A., & Marks, T. J. (2010). Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2). Acta Crystallographica Section E: Structure Reports Online, 66(3), m257. https://doi.org/10.1107/S1600536810003697