Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2)

Massimiliano Delferro, Michael P. Weberski, Brandon A. Rodriguez, Tobin J Marks

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title complex, [Ni4(C36H40N 2O2)2(OH)4(C3H 9OP)2(H2O)4]·2C 4H10O·2C3H9OP·2H 2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octa-hedral geometry.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number3
DOIs
Publication statusPublished - 2010

Fingerprint

cubane
Naphthalene
naphthalene
phosphines
Ether
Oxides
hydroxides
Metal ions
Ethers
ethers
metal ions
Atoms
Defects
oxides
Geometry
Water
defects
geometry
water
atoms

Keywords

  • Data-to-parameter ratio = 15.0
  • Hatom completeness 98%
  • Mean σ(C-C) = 0.005 Å
  • R factor = 0.046
  • Single-crystal X-ray study
  • T = 100 K
  • WR factor = 0.162

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

@article{0a22618b770b47ef9ef4ce20c23cd68c,
title = "Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2)",
abstract = "The title complex, [Ni4(C36H40N 2O2)2(OH)4(C3H 9OP)2(H2O)4]·2C 4H10O·2C3H9OP·2H 2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octa-hedral geometry.",
keywords = "Data-to-parameter ratio = 15.0, Hatom completeness 98{\%}, Mean σ(C-C) = 0.005 {\AA}, R factor = 0.046, Single-crystal X-ray study, T = 100 K, WR factor = 0.162",
author = "Massimiliano Delferro and Weberski, {Michael P.} and Rodriguez, {Brandon A.} and Marks, {Tobin J}",
year = "2010",
doi = "10.1107/S1600536810003697",
language = "English",
volume = "66",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "3",

}

TY - JOUR

T1 - Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2)

AU - Delferro, Massimiliano

AU - Weberski, Michael P.

AU - Rodriguez, Brandon A.

AU - Marks, Tobin J

PY - 2010

Y1 - 2010

N2 - The title complex, [Ni4(C36H40N 2O2)2(OH)4(C3H 9OP)2(H2O)4]·2C 4H10O·2C3H9OP·2H 2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octa-hedral geometry.

AB - The title complex, [Ni4(C36H40N 2O2)2(OH)4(C3H 9OP)2(H2O)4]·2C 4H10O·2C3H9OP·2H 2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octa-hedral geometry.

KW - Data-to-parameter ratio = 15.0

KW - Hatom completeness 98%

KW - Mean σ(C-C) = 0.005 Å

KW - R factor = 0.046

KW - Single-crystal X-ray study

KW - T = 100 K

KW - WR factor = 0.162

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U2 - 10.1107/S1600536810003697

DO - 10.1107/S1600536810003697

M3 - Article

VL - 66

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 3

ER -