Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2)

Massimiliano Delferro, Michael P. Weberski, Brandon A. Rodriguez, Tobin J Marks

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

The title complex, [Ni4(C36H40N 2O2)2(OH)4(C3H 9OP)2(H2O)4]·2C 4H10O·2C3H9OP·2H 2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octa-hedral geometry.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number3
DOIs
Publication statusPublished - 2010

Fingerprint

cubane
Naphthalene
naphthalene
phosphines
Ether
Oxides
hydroxides
Metal ions
Ethers
ethers
metal ions
Atoms
Defects
oxides
Geometry
Water
defects
geometry
water
atoms

Keywords

  • Data-to-parameter ratio = 15.0
  • Hatom completeness 98%
  • Mean σ(C-C) = 0.005 Å
  • R factor = 0.046
  • Single-crystal X-ray study
  • T = 100 K
  • WR factor = 0.162

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2). / Delferro, Massimiliano; Weberski, Michael P.; Rodriguez, Brandon A.; Marks, Tobin J.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 3, 2010.

Research output: Contribution to journal › Article

Delferro, M, Weberski, MP, Rodriguez, BA & Marks, TJ 2010, 'Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2)', Acta Crystallographica Section E: Structure Reports Online, vol. 66, no. 3. https://doi.org/10.1107/S1600536810003697
Delferro M, Weberski MP, Rodriguez BA, Marks TJ. Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2). Acta Crystallographica Section E: Structure Reports Online. 2010;66(3). https://doi.org/10.1107/S1600536810003697
Delferro, Massimiliano ; Weberski, Michael P. ; Rodriguez, Brandon A. ; Marks, Tobin J. / Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2). In: Acta Crystallographica Section E: Structure Reports Online. 2010 ; Vol. 66, No. 3.
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