TY - JOUR
T1 - Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2)
AU - Delferro, Massimiliano
AU - Weberski, Michael P.
AU - Rodriguez, Brandon A.
AU - Marks, Tobin J.
N1 - Copyright:
Copyright 2010 Elsevier B.V., All rights reserved.
PY - 2010
Y1 - 2010
N2 - The title complex, [Ni4(C36H40N 2O2)2(OH)4(C3H 9OP)2(H2O)4]·2C 4H10O·2C3H9OP·2H 2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octa-hedral geometry.
AB - The title complex, [Ni4(C36H40N 2O2)2(OH)4(C3H 9OP)2(H2O)4]·2C 4H10O·2C3H9OP·2H 2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octa-hedral geometry.
KW - Data-to-parameter ratio = 15.0
KW - Hatom completeness 98%
KW - Mean σ(C-C) = 0.005 Å
KW - R factor = 0.046
KW - Single-crystal X-ray study
KW - T = 100 K
KW - WR factor = 0.162
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U2 - 10.1107/S1600536810003697
DO - 10.1107/S1600536810003697
M3 - Article
C2 - 21580211
AN - SCOPUS:77949387739
VL - 66
SP - m257
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 3
ER -