Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2)

Massimiliano Delferro, Michael P. Weberski, Brandon A. Rodriguez, Tobin J. Marks

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title complex, [Ni4(C36H40N 2O2)2(OH)4(C3H 9OP)2(H2O)4]·2C 4H10O·2C3H9OP·2H 2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octa-hedral geometry.

Original languageEnglish
Pages (from-to)m257
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number3
DOIs
Publication statusPublished - Mar 19 2010

Keywords

  • Data-to-parameter ratio = 15.0
  • Hatom completeness 98%
  • Mean σ(C-C) = 0.005 Å
  • R factor = 0.046
  • Single-crystal X-ray study
  • T = 100 K
  • WR factor = 0.162

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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