Tetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2)

Massimiliano Delferro; Michael P. Weberski; Brandon A. Rodriguez; Tobin J. Marks

doi:10.1107/S1600536810003697

Tetraaquabis{μ₂-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ₃-hydroxido-di-μ₂- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2)

Massimiliano Delferro, Michael P. Weberski, Brandon A. Rodriguez, Tobin J. Marks

Northwestern University

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title complex, [Ni₄(C₃₆H₄₀N ₂O₂)₂(OH)₄(C₃H ₉OP)₂(H₂O)₄]·2C ₄H₁₀O·2C₃H₉OP·2H ₂O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each Ni^II atom adopts a distorted octa-hedral geometry.

Original language	English
Pages (from-to)	m257
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	3
DOIs	https://doi.org/10.1107/S1600536810003697
Publication status	Published - 2010

Keywords

Data-to-parameter ratio = 15.0
Hatom completeness 98%
Mean σ(C-C) = 0.005 Å
R factor = 0.046
Single-crystal X-ray study
T = 100 K
WR factor = 0.162

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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Delferro, M., Weberski, M. P., Rodriguez, B. A., & Marks, T. J. (2010). Tetraaquabis{μ₂-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ₃-hydroxido-di-μ₂- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2). Acta Crystallographica Section E: Structure Reports Online, 66(3), m257. https://doi.org/10.1107/S1600536810003697

Tetraaquabis{μ₂-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ₃-hydroxido-di-μ₂- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2). / Delferro, Massimiliano; Weberski, Michael P.; Rodriguez, Brandon A.; Marks, Tobin J.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 3, 2010, p. m257.

Research output: Contribution to journal › Article › peer-review

Delferro, M, Weberski, MP, Rodriguez, BA & Marks, TJ 2010, 'Tetraaquabis{μ₂-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ₃-hydroxido-di-μ₂- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2)', Acta Crystallographica Section E: Structure Reports Online, vol. 66, no. 3, pp. m257. https://doi.org/10.1107/S1600536810003697

Delferro M, Weberski MP, Rodriguez BA, Marks TJ. Tetraaquabis{μ₂-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ₃-hydroxido-di-μ₂- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2). Acta Crystallographica Section E: Structure Reports Online. 2010;66(3):m257. https://doi.org/10.1107/S1600536810003697

Delferro, Massimiliano ; Weberski, Michael P. ; Rodriguez, Brandon A. ; Marks, Tobin J. / Tetraaquabis{μ₂-2,7-bis[(2,6-diisopropylphenyl)iminomethyl] naphthalene-1,8-diolato}di-μ₃-hydroxido-di-μ₂- hydroxidobis-(trimethyl-phosphine oxide)tetranickel(II)-trimethylphosphine oxidediethyl ether-water (1/2/2/2). In: Acta Crystallographica Section E: Structure Reports Online. 2010 ; Vol. 66, No. 3. pp. m257.

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abstract = "The title complex, [Ni4(C36H40N 2O2)2(OH)4(C3H 9OP)2(H2O)4]·2C 4H10O·2C3H9OP·2H 2O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each NiII atom adopts a distorted octa-hedral geometry.",

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