The branching ratio between reaction and relaxation in the removal of H2O from its |04>- vibrational state in collisions with H atoms

Peter W. Barnes, Ian R. Sims, Ian W M Smith, György Lendvay, George C Schatz

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Experiments were carried out to determine the branching ratio between reaction and relaxation for loss from the |04>- vibrational state of H2O in collisions with H atoms. Three sets of experiments were repeated several times with different concentrations of H atoms and H2O molecules present in the gas mixtures. The results lead to the conclusion that reaction and energy transfer make comparable contributions to collisions between water in the |04>- state and thermal hydrogen atoms.

Original languageEnglish
Pages (from-to)4586-4592
Number of pages7
JournalJournal of Chemical Physics
Volume115
Issue number10
DOIs
Publication statusPublished - Sep 8 2001

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

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