The CH+H reaction studied with quantum-mechanical and classical trajectory calculations

Rob Van Harrevelt, Marc C. Van Hemert, George C Schatz

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

The lowest excited 1Σ g +-type electronic state of C 2, the B′ state, had been studied for years. Investigating microwave discharge of various hydrocarbon mixtures by a high-resolution Fourier-transform infrared (FTIR) spectrometers, the B′ 1Σ g +1π u emission of C 2 in the infrared was observed. This paper discusses the observation of laser induced fluorescence (LIF) spectra of the D→B′ and C→A transitions of C 2 in a solid Ne matrix.

Original languageEnglish
Pages (from-to)6002-6011
Number of pages10
JournalJournal of Chemical Physics
Volume116
Issue number14
DOIs
Publication statusPublished - Apr 8 2002

Fingerprint

Infrared spectrometers
infrared spectrometers
Electronic states
Hydrocarbons
laser induced fluorescence
Fourier transforms
hydrocarbons
Fluorescence
Microwaves
Trajectories
trajectories
methylidyne
Infrared radiation
microwaves
Lasers
high resolution
matrices
electronics

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

The CH+H reaction studied with quantum-mechanical and classical trajectory calculations. / Van Harrevelt, Rob; Van Hemert, Marc C.; Schatz, George C.

In: Journal of Chemical Physics, Vol. 116, No. 14, 08.04.2002, p. 6002-6011.

Research output: Contribution to journalArticle

Van Harrevelt, Rob ; Van Hemert, Marc C. ; Schatz, George C. / The CH+H reaction studied with quantum-mechanical and classical trajectory calculations. In: Journal of Chemical Physics. 2002 ; Vol. 116, No. 14. pp. 6002-6011.
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