The effect of intramolecular coupling on the optical susceptibilities of a two-level molecule

J. L. Paz; M. García-Sucre; E. Squitieri; V. Mujica

doi:10.1016/0009-2614(93)E1357-M

The effect of intramolecular coupling on the optical susceptibilities of a two-level molecule

J. L. Paz, M. García-Sucre, E. Squitieri, V. Mujica

Arizona State University

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The effect of intramolecular coupling on the optical susceptibilities up to third order in the external field is studied using a model molecule consisting of two coupled harmonic curves of electronic energies with minima displaced in energy and nuclear coordinates. We consider two vibrational states and we include non-adiabatic effects for this two-state model. We have calculated the absorption for one-, two- and three-photon processes for values of the parameters characteristic of large organic molecules diluted in water. Our results show that intramolecular coupling has a large effect on this property.

Original language	English
Pages (from-to)	333-341
Number of pages	9
Journal	Chemical Physics Letters
Volume	217
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(93)E1357-M
Publication status	Published - Jan 14 1994

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "The effect of intramolecular coupling on the optical susceptibilities of a two-level molecule",

abstract = "The effect of intramolecular coupling on the optical susceptibilities up to third order in the external field is studied using a model molecule consisting of two coupled harmonic curves of electronic energies with minima displaced in energy and nuclear coordinates. We consider two vibrational states and we include non-adiabatic effects for this two-state model. We have calculated the absorption for one-, two- and three-photon processes for values of the parameters characteristic of large organic molecules diluted in water. Our results show that intramolecular coupling has a large effect on this property.",

author = "Paz, {J. L.} and M. Garc{\'i}a-Sucre and E. Squitieri and V. Mujica",

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AU - García-Sucre, M.

AU - Squitieri, E.

AU - Mujica, V.

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AB - The effect of intramolecular coupling on the optical susceptibilities up to third order in the external field is studied using a model molecule consisting of two coupled harmonic curves of electronic energies with minima displaced in energy and nuclear coordinates. We consider two vibrational states and we include non-adiabatic effects for this two-state model. We have calculated the absorption for one-, two- and three-photon processes for values of the parameters characteristic of large organic molecules diluted in water. Our results show that intramolecular coupling has a large effect on this property.

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