The Ferraquinone-Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity

Alexander Dauth, Urs Gellrich, Yael Diskin-Posner, Yehoshoa Ben-David, David Milstein

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A ferraquinone-ferrahydroquinone organometallic redox couple was prepared and characterized. Intricate cooperativity of the metal was observed with different positions on the ligand. This allowed cooperative activation of small molecules like molecular hydrogen, oxygen, and bromine. Likewise, dehydrogenation of alcohols was achieved through 1,6 metal-ligand cooperation.

Original languageEnglish
Pages (from-to)2799-2807
Number of pages9
JournalJournal of the American Chemical Society
Volume139
Issue number7
DOIs
Publication statusPublished - Feb 22 2017

Fingerprint

Metals
Ligands
Bromine
Organometallics
Dehydrogenation
Oxidation-Reduction
Hydrogen
Alcohols
Chemical activation
Oxygen
Molecules

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

The Ferraquinone-Ferrahydroquinone Couple : Combining Quinonic and Metal-Based Reactivity. / Dauth, Alexander; Gellrich, Urs; Diskin-Posner, Yael; Ben-David, Yehoshoa; Milstein, David.

In: Journal of the American Chemical Society, Vol. 139, No. 7, 22.02.2017, p. 2799-2807.

Research output: Contribution to journalArticle

Dauth, Alexander ; Gellrich, Urs ; Diskin-Posner, Yael ; Ben-David, Yehoshoa ; Milstein, David. / The Ferraquinone-Ferrahydroquinone Couple : Combining Quinonic and Metal-Based Reactivity. In: Journal of the American Chemical Society. 2017 ; Vol. 139, No. 7. pp. 2799-2807.
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