The first 2,3-dihydro-1 H-[1,2,4] triphosphole

Vinicius Caliman, Monte Helm, Peter B. Hitchcock, Cameron Jones, John F. Nixon

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

Protonation of the lithium triphospha-cyclopentenyl salt Li (P3C2B′2RR′) (R = (Me3Si)2CH-, R′ = Bu″) with HCl affords the new 2.3-dihydro-1H-[1,2,4] triphosphole P3C2Bu′2(H) (Bu″)CH(SiMe3)2 which has been structurally characterised as its [W(CO)5] complex.

Original languageEnglish
Pages (from-to)198-201
Number of pages4
JournalJournal of Organometallic Chemistry
Volume650
Issue number1-2
DOIs
Publication statusPublished - May 1 2002

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Protonation
Carbon Monoxide
Lithium
Salts
lithium
methylidyne
salts

Keywords

  • Complexes
  • Lithium
  • Triphospha-cyclopentenyl
  • Triphosphole

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

The first 2,3-dihydro-1 H-[1,2,4] triphosphole. / Caliman, Vinicius; Helm, Monte; Hitchcock, Peter B.; Jones, Cameron; Nixon, John F.

In: Journal of Organometallic Chemistry, Vol. 650, No. 1-2, 01.05.2002, p. 198-201.

Research output: Contribution to journal › Article

Caliman, V, Helm, M, Hitchcock, PB, Jones, C & Nixon, JF 2002, 'The first 2,3-dihydro-1 H-[1,2,4] triphosphole', Journal of Organometallic Chemistry, vol. 650, no. 1-2, pp. 198-201. https://doi.org/10.1016/S0022-328X(02)01227-5
Caliman V, Helm M, Hitchcock PB, Jones C, Nixon JF. The first 2,3-dihydro-1 H-[1,2,4] triphosphole. Journal of Organometallic Chemistry. 2002 May 1;650(1-2):198-201. https://doi.org/10.1016/S0022-328X(02)01227-5
Caliman, Vinicius ; Helm, Monte ; Hitchcock, Peter B. ; Jones, Cameron ; Nixon, John F. / The first 2,3-dihydro-1 H-[1,2,4] triphosphole. In: Journal of Organometallic Chemistry. 2002 ; Vol. 650, No. 1-2. pp. 198-201.
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