The first 2,3-dihydro-1 H-[1,2,4] triphosphole

Vinicius Caliman; Monte Helm; Peter B. Hitchcock; Cameron Jones; John F. Nixon

doi:10.1016/S0022-328X(02)01227-5

The first 2,3-dihydro-1 H-[1,2,4] triphosphole

Vinicius Caliman, Monte Helm, Peter B. Hitchcock, Cameron Jones, John F. Nixon

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

Protonation of the lithium triphospha-cyclopentenyl salt Li (P₃C₂B′₂RR′) (R = (Me₃Si)₂CH-, R′ = Bu″) with HCl affords the new 2.3-dihydro-1H-[1,2,4] triphosphole P₃C₂Bu′₂(H) (Bu″)CH(SiMe₃)₂ which has been structurally characterised as its [W(CO)₅] complex.

Original language	English
Pages (from-to)	198-201
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	650
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(02)01227-5
Publication status	Published - May 1 2002

Keywords

Complexes
Lithium
Triphospha-cyclopentenyl
Triphosphole

ASJC Scopus subject areas

Biochemistry
Inorganic Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-328X(02)01227-5

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Cite this

Caliman, V., Helm, M., Hitchcock, P. B., Jones, C., & Nixon, J. F. (2002). The first 2,3-dihydro-1 H-[1,2,4] triphosphole. Journal of Organometallic Chemistry, 650(1-2), 198-201. https://doi.org/10.1016/S0022-328X(02)01227-5

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abstract = "Protonation of the lithium triphospha-cyclopentenyl salt Li (P3C2B′2RR′) (R = (Me3Si)2CH-, R′ = Bu″) with HCl affords the new 2.3-dihydro-1H-[1,2,4] triphosphole P3C2Bu′2(H) (Bu″)CH(SiMe3)2 which has been structurally characterised as its [W(CO)5] complex.",

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AU - Nixon, John F.

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AB - Protonation of the lithium triphospha-cyclopentenyl salt Li (P3C2B′2RR′) (R = (Me3Si)2CH-, R′ = Bu″) with HCl affords the new 2.3-dihydro-1H-[1,2,4] triphosphole P3C2Bu′2(H) (Bu″)CH(SiMe3)2 which has been structurally characterised as its [W(CO)5] complex.

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