The first 2,3-dihydro-1 H-[1,2,4] triphosphole

Vinicius Caliman; Monte L. Helm; Peter B. Hitchcock; Cameron Jones; John F. Nixon

doi:10.1016/S0022-328X(02)01227-5

The first 2,3-dihydro-1 H-[1,2,4] triphosphole

Vinicius Caliman, Monte L. Helm, Peter B. Hitchcock, Cameron Jones, John F. Nixon

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Protonation of the lithium triphospha-cyclopentenyl salt Li (P₃C₂B′₂RR′) (R = (Me₃Si)₂CH-, R′ = Bu″) with HCl affords the new 2.3-dihydro-1H-[1,2,4] triphosphole P₃C₂Bu′₂(H) (Bu″)CH(SiMe₃)₂ which has been structurally characterised as its [W(CO)₅] complex.

Original language	English
Pages (from-to)	198-201
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	650
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(02)01227-5
Publication status	Published - May 1 2002

Keywords

Complexes
Lithium
Triphospha-cyclopentenyl
Triphosphole

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-328X(02)01227-5

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Cite this

@article{0c1efad3ae4b44c498e22c850a6058e6,

title = "The first 2,3-dihydro-1 H-[1,2,4] triphosphole",

abstract = "Protonation of the lithium triphospha-cyclopentenyl salt Li (P3C2B′2RR′) (R = (Me3Si)2CH-, R′ = Bu″) with HCl affords the new 2.3-dihydro-1H-[1,2,4] triphosphole P3C2Bu′2(H) (Bu″)CH(SiMe3)2 which has been structurally characterised as its [W(CO)5] complex.",

keywords = "Complexes, Lithium, Triphospha-cyclopentenyl, Triphosphole",

author = "Vinicius Caliman and Helm, {Monte L.} and Hitchcock, {Peter B.} and Cameron Jones and Nixon, {John F.}",

note = "Funding Information: We thank both CNPq and FAPEMIG for financial support (for V.C.) and EPSRC for a post-doctoral grant (for M.L.H.) and for their continuing support (to J.F.N.) for phospha-organometallic chemistry.",

year = "2002",

month = may,

day = "1",

doi = "10.1016/S0022-328X(02)01227-5",

language = "English",

volume = "650",

pages = "198--201",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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number = "1-2",

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TY - JOUR

T1 - The first 2,3-dihydro-1 H-[1,2,4] triphosphole

AU - Caliman, Vinicius

AU - Helm, Monte L.

AU - Hitchcock, Peter B.

AU - Jones, Cameron

AU - Nixon, John F.

N1 - Funding Information: We thank both CNPq and FAPEMIG for financial support (for V.C.) and EPSRC for a post-doctoral grant (for M.L.H.) and for their continuing support (to J.F.N.) for phospha-organometallic chemistry.

PY - 2002/5/1

Y1 - 2002/5/1

N2 - Protonation of the lithium triphospha-cyclopentenyl salt Li (P3C2B′2RR′) (R = (Me3Si)2CH-, R′ = Bu″) with HCl affords the new 2.3-dihydro-1H-[1,2,4] triphosphole P3C2Bu′2(H) (Bu″)CH(SiMe3)2 which has been structurally characterised as its [W(CO)5] complex.

AB - Protonation of the lithium triphospha-cyclopentenyl salt Li (P3C2B′2RR′) (R = (Me3Si)2CH-, R′ = Bu″) with HCl affords the new 2.3-dihydro-1H-[1,2,4] triphosphole P3C2Bu′2(H) (Bu″)CH(SiMe3)2 which has been structurally characterised as its [W(CO)5] complex.

KW - Complexes

KW - Lithium

KW - Triphospha-cyclopentenyl

KW - Triphosphole

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