Abstract
The first electrochemical study of a compound containing a Si=C double bond, i.e., (t-BuMe2Si)(Me3-Si)Si=2-Ad, reveals an extremely low oxidation potential of 0.28 V (vs Ag/AgCl), which is comparable to those of of the best known organic electron donors.
| Original language | English |
|---|---|
| Pages (from-to) | 921-923 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 23 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Feb 16 2004 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Bendikov, M., Kravchenko, V., Apeloig, Y., & Becker, J. Y. (2004). The first electrochemical study of a silene. An unusually low oxidation potential, comparable to those of strong organic π-electron donors. Organometallics, 23(4), 921-923. https://doi.org/10.1021/om0341909