The first electrochemical study of a silene. An unusually low oxidation potential, comparable to those of strong organic π-electron donors

Michael Bendikov; Victoria Kravchenko; Yitzhak Apeloig; James Y. Becker

doi:10.1021/om0341909

The first electrochemical study of a silene. An unusually low oxidation potential, comparable to those of strong organic π-electron donors

Michael Bendikov, Victoria Kravchenko, Yitzhak Apeloig, James Y. Becker

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The first electrochemical study of a compound containing a Si=C double bond, i.e., (t-BuMe₂Si)(Me₃-Si)Si=2-Ad, reveals an extremely low oxidation potential of 0.28 V (vs Ag/AgCl), which is comparable to those of of the best known organic electron donors.

Original language	English
Pages (from-to)	921-923
Number of pages	3
Journal	Organometallics
Volume	23
Issue number	4
DOIs	https://doi.org/10.1021/om0341909
Publication status	Published - Feb 16 2004

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "The first electrochemical study of a compound containing a Si=C double bond, i.e., (t-BuMe2Si)(Me3-Si)Si=2-Ad, reveals an extremely low oxidation potential of 0.28 V (vs Ag/AgCl), which is comparable to those of of the best known organic electron donors.",

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AU - Becker, James Y.

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AB - The first electrochemical study of a compound containing a Si=C double bond, i.e., (t-BuMe2Si)(Me3-Si)Si=2-Ad, reveals an extremely low oxidation potential of 0.28 V (vs Ag/AgCl), which is comparable to those of of the best known organic electron donors.

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The first electrochemical study of a silene. An unusually low oxidation potential, comparable to those of strong organic π-electron donors

Abstract

ASJC Scopus subject areas

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