Abstract
Anhydrous, anaerobic electrocrystallization techniques have afforded (TSeT)F0.25Cl0.50, the first organic molecular metal to contain off-axis fluoride counterions. This material crystallizes in a unique tetragonal motif with stacks of canted TSeT+0.75 molecules. Disordered chloride and fluoride counterions are found in two different types of channels extending parallel to the stacking axis. Interchain Se...Se interactions are shorter than in the analogous (TSeT+y) (X-)y salts (X- = Cl-, Br-, I-). These structural changes are reflected in the electrical [σ (300K) = 1700 S/cm]; σ (40K) = 7000 S/cm, thermoelectrical, and optical properties of this new organic metal.
Original language | English |
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Pages (from-to) | 2659-2663 |
Number of pages | 5 |
Journal | Synthetic Metals |
Volume | 42 |
Issue number | 3 |
DOIs | |
Publication status | Published - May 29 1991 |
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ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Materials Chemistry
- Polymers and Plastics
Cite this
The first molecular metal containing fluoride counterions. / Schlueter, J. A.; Orihashi, Y.; Kanatzidis, Mercouri G; Liang, W. B.; Marks, Tobin J; DeGroot, D. C.; Marcy, H. O.; McCarthy, W. J.; Kannewurf, C. R.
In: Synthetic Metals, Vol. 42, No. 3, 29.05.1991, p. 2659-2663.Research output: Contribution to journal › Article
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TY - JOUR
T1 - The first molecular metal containing fluoride counterions
AU - Schlueter, J. A.
AU - Orihashi, Y.
AU - Kanatzidis, Mercouri G
AU - Liang, W. B.
AU - Marks, Tobin J
AU - DeGroot, D. C.
AU - Marcy, H. O.
AU - McCarthy, W. J.
AU - Kannewurf, C. R.
PY - 1991/5/29
Y1 - 1991/5/29
N2 - Anhydrous, anaerobic electrocrystallization techniques have afforded (TSeT)F0.25Cl0.50, the first organic molecular metal to contain off-axis fluoride counterions. This material crystallizes in a unique tetragonal motif with stacks of canted TSeT+0.75 molecules. Disordered chloride and fluoride counterions are found in two different types of channels extending parallel to the stacking axis. Interchain Se...Se interactions are shorter than in the analogous (TSeT+y) (X-)y salts (X- = Cl-, Br-, I-). These structural changes are reflected in the electrical [σ (300K) = 1700 S/cm]; σ (40K) = 7000 S/cm, thermoelectrical, and optical properties of this new organic metal.
AB - Anhydrous, anaerobic electrocrystallization techniques have afforded (TSeT)F0.25Cl0.50, the first organic molecular metal to contain off-axis fluoride counterions. This material crystallizes in a unique tetragonal motif with stacks of canted TSeT+0.75 molecules. Disordered chloride and fluoride counterions are found in two different types of channels extending parallel to the stacking axis. Interchain Se...Se interactions are shorter than in the analogous (TSeT+y) (X-)y salts (X- = Cl-, Br-, I-). These structural changes are reflected in the electrical [σ (300K) = 1700 S/cm]; σ (40K) = 7000 S/cm, thermoelectrical, and optical properties of this new organic metal.
UR - http://www.scopus.com/inward/record.url?scp=0026155415&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0026155415&partnerID=8YFLogxK
U2 - 10.1016/0379-6779(91)91446-H
DO - 10.1016/0379-6779(91)91446-H
M3 - Article
AN - SCOPUS:0026155415
VL - 42
SP - 2659
EP - 2663
JO - Synthetic Metals
JF - Synthetic Metals
SN - 0379-6779
IS - 3
ER -