The first molecular metal containing fluoride counterions

J. A. Schlueter, Y. Orihashi, Mercouri G Kanatzidis, W. B. Liang, Tobin J Marks, D. C. DeGroot, H. O. Marcy, W. J. McCarthy, C. R. Kannewurf

Research output: Contribution to journal › Article

1 Citation (Scopus)

Abstract

Anhydrous, anaerobic electrocrystallization techniques have afforded (TSeT)F0.25Cl0.50, the first organic molecular metal to contain off-axis fluoride counterions. This material crystallizes in a unique tetragonal motif with stacks of canted TSeT+0.75 molecules. Disordered chloride and fluoride counterions are found in two different types of channels extending parallel to the stacking axis. Interchain Se...Se interactions are shorter than in the analogous (TSeT+y) (X-)y salts (X- = Cl-, Br-, I-). These structural changes are reflected in the electrical [σ (300K) = 1700 S/cm]; σ (40K) = 7000 S/cm, thermoelectrical, and optical properties of this new organic metal.

Original languageEnglish
Pages (from-to)2659-2663
Number of pages5
JournalSynthetic Metals
Volume42
Issue number3
DOIs
Publication statusPublished - May 29 1991

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metal fluorides
Fluorides
fluorides
Metals
metals
Chlorides
Optical properties
Salts
chlorides
salts
optical properties
Molecules
molecules
interactions

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Schlueter, J. A., Orihashi, Y., Kanatzidis, M. G., Liang, W. B., Marks, T. J., DeGroot, D. C., ... Kannewurf, C. R. (1991). The first molecular metal containing fluoride counterions. Synthetic Metals, 42(3), 2659-2663. https://doi.org/10.1016/0379-6779(91)91446-H

The first molecular metal containing fluoride counterions. / Schlueter, J. A.; Orihashi, Y.; Kanatzidis, Mercouri G; Liang, W. B.; Marks, Tobin J; DeGroot, D. C.; Marcy, H. O.; McCarthy, W. J.; Kannewurf, C. R.

In: Synthetic Metals, Vol. 42, No. 3, 29.05.1991, p. 2659-2663.

Research output: Contribution to journal › Article

Schlueter, JA, Orihashi, Y, Kanatzidis, MG, Liang, WB, Marks, TJ, DeGroot, DC, Marcy, HO, McCarthy, WJ & Kannewurf, CR 1991, 'The first molecular metal containing fluoride counterions', Synthetic Metals, vol. 42, no. 3, pp. 2659-2663. https://doi.org/10.1016/0379-6779(91)91446-H
Schlueter JA, Orihashi Y, Kanatzidis MG, Liang WB, Marks TJ, DeGroot DC et al. The first molecular metal containing fluoride counterions. Synthetic Metals. 1991 May 29;42(3):2659-2663. https://doi.org/10.1016/0379-6779(91)91446-H
Schlueter, J. A. ; Orihashi, Y. ; Kanatzidis, Mercouri G ; Liang, W. B. ; Marks, Tobin J ; DeGroot, D. C. ; Marcy, H. O. ; McCarthy, W. J. ; Kannewurf, C. R. / The first molecular metal containing fluoride counterions. In: Synthetic Metals. 1991 ; Vol. 42, No. 3. pp. 2659-2663.
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AU - Marks, Tobin J

AU - DeGroot, D. C.

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AB - Anhydrous, anaerobic electrocrystallization techniques have afforded (TSeT)F0.25Cl0.50, the first organic molecular metal to contain off-axis fluoride counterions. This material crystallizes in a unique tetragonal motif with stacks of canted TSeT+0.75 molecules. Disordered chloride and fluoride counterions are found in two different types of channels extending parallel to the stacking axis. Interchain Se...Se interactions are shorter than in the analogous (TSeT+y) (X-)y salts (X- = Cl-, Br-, I-). These structural changes are reflected in the electrical [σ (300K) = 1700 S/cm]; σ (40K) = 7000 S/cm, thermoelectrical, and optical properties of this new organic metal.

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