The growth of silicon nitride crystalline films using microwave plasma enhanced chemical vapor deposition

K. J. Grannen, F. Xiang, Robert P. H. Chang

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Crystalline thin films of silicon nitride have been grown on a variety of substrates by microwave plasma-enhanced chemical vapor deposition using N2, O2, and CH4 gases at a temperature of 800 °C. X-ray diffraction and Rutherford backscattering measurements indicate the deposits are stoichiometric silicon nitride with varying amounts of the a and β phases. Scanning electron microscopy imaging indicates β—Si3N4 possesses sixfold symmetry with particle sizes in the submicron range. In one experiment, the silicon necessary for growth comes from the single crystal silicon substrate due to etching/sputtering by the nitrogen plasma. The dependence of the grain size on the methane concentration is investigated. In another experiment, an organo-silicon source, methoxytrimethylsilane, is used to grow silicon nitride with controlled introduction of the silicon necessary for growth. Thin crystalline films are deposited at rates of 0.1 μm/h as determined by profilometry. A growth mechanism for both cases is proposed.

Original languageEnglish
Pages (from-to)2341-2348
Number of pages8
JournalJournal of Materials Research
Volume9
Issue number9
DOIs
Publication statusPublished - 1994

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ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Condensed Matter Physics
  • Mechanical Engineering

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