The influence of guanine on DNA hole transport efficiency

Frederick D. Lewis, Pierre Daublain, Boiko Cohen, Josh Vura-Weis, Michael R. Wasielewski

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

(Figure Presented) Stopover at G base: The efficiency of photoinduced charge separation between donor and acceptor chromophores separated by a polyadenine sequence containing a single guanine (G) is sensitive to the location of G and the total length of the polypurine sequence. Quantum yields provide support for a stepwise mechanism in which G serves as a temporary resting place in the overall process (Sa: stilbenedicarboxamide electron acceptor, Sd: stilbenediether electron donor).

Original languageEnglish
Pages (from-to)3798-3800
Number of pages3
JournalAngewandte Chemie - International Edition
Volume47
Issue number20
DOIs
Publication statusPublished - May 5 2008

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Keywords

  • Charge separation
  • DNA conjugates
  • Electron transfer
  • Guanine
  • Hole transport

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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