The M(dddt)2 family of conducting complexes: [Ni(dddt)2]3(AuBr2)2, the first quasi-two-dimensional metal stable down to at least 1.3 K

Lyudmila A. Kushch, Viktor V. Gritsenko, Lev I. Buravov, Anna G. Khomenko, Gennadii V. Shilov, Oleg A. Dyachenko, Vladimir A. Merzhanov, Eduard B. Yagubskii, Roger Rousseau, Enric Canadell

Research output: Contribution to journalArticle

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Abstract

The first stable molecular metal, [Ni(dddt2]3(AuBr2)2, among the M(dddt)2 family of conducting charge-transfer salts has been prepared and its crystal structure has been solved by X-ray analysis. The origin of the metallic conductivity of [Ni(dddt)2]3(AuBr2)2 as well as the stability of this salt with respect to metal-to-insulator transitions is explained on the basis of tight-binding band structure calculations.

Original languageEnglish
Pages (from-to)1633-1638
Number of pages6
JournalJournal of Materials Chemistry
Volume5
Issue number10
DOIs
Publication statusPublished - 1995

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Salts
Metals
salts
conduction
X ray analysis
Band structure
metals
Charge transfer
Crystal structure
charge transfer
insulators
conductivity
crystal structure
x rays

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry
  • Materials Science(all)
  • Physical and Theoretical Chemistry

Cite this

Kushch, L. A., Gritsenko, V. V., Buravov, L. I., Khomenko, A. G., Shilov, G. V., Dyachenko, O. A., ... Canadell, E. (1995). The M(dddt)2 family of conducting complexes: [Ni(dddt)2]3(AuBr2)2, the first quasi-two-dimensional metal stable down to at least 1.3 K. Journal of Materials Chemistry, 5(10), 1633-1638. https://doi.org/10.1039/JM9950501633

The M(dddt)2 family of conducting complexes : [Ni(dddt)2]3(AuBr2)2, the first quasi-two-dimensional metal stable down to at least 1.3 K. / Kushch, Lyudmila A.; Gritsenko, Viktor V.; Buravov, Lev I.; Khomenko, Anna G.; Shilov, Gennadii V.; Dyachenko, Oleg A.; Merzhanov, Vladimir A.; Yagubskii, Eduard B.; Rousseau, Roger; Canadell, Enric.

In: Journal of Materials Chemistry, Vol. 5, No. 10, 1995, p. 1633-1638.

Research output: Contribution to journalArticle

Kushch, LA, Gritsenko, VV, Buravov, LI, Khomenko, AG, Shilov, GV, Dyachenko, OA, Merzhanov, VA, Yagubskii, EB, Rousseau, R & Canadell, E 1995, 'The M(dddt)2 family of conducting complexes: [Ni(dddt)2]3(AuBr2)2, the first quasi-two-dimensional metal stable down to at least 1.3 K', Journal of Materials Chemistry, vol. 5, no. 10, pp. 1633-1638. https://doi.org/10.1039/JM9950501633
Kushch, Lyudmila A. ; Gritsenko, Viktor V. ; Buravov, Lev I. ; Khomenko, Anna G. ; Shilov, Gennadii V. ; Dyachenko, Oleg A. ; Merzhanov, Vladimir A. ; Yagubskii, Eduard B. ; Rousseau, Roger ; Canadell, Enric. / The M(dddt)2 family of conducting complexes : [Ni(dddt)2]3(AuBr2)2, the first quasi-two-dimensional metal stable down to at least 1.3 K. In: Journal of Materials Chemistry. 1995 ; Vol. 5, No. 10. pp. 1633-1638.
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