Abstract
Use of trimethylphosphine-palladium complexes renders the product-forming step in palladium-catalysed methoxycarbonylation of benzyl chloride or iodobenzene rate-determining and allows for its direct observation; the product-forming step is alcoholysis of an acylpalladium complex and not reductive elimination of a methoxycarbonylpalladium intermediate.
| Original language | English |
|---|---|
| Pages (from-to) | 817-818 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - 1986 |
ASJC Scopus subject areas
- Molecular Medicine