Abstract
A synergistic effect between Au and Co has been successfully demonstrated in the selective oxidation of Ethylbenzene. Solubilized Au nanoclusters are initiators different from traditional free radical initiators. Cyclooctene hydroperoxide is most likely to be the mediator between Au and Co. Some oxidation products from c-C8= oxidation can increase the efficiency of peroxide initiator.
| Original language | English |
|---|---|
| Title of host publication | Catalysis and Reaction Engineering Division 2017 - Core Programming Area at the 2017 AIChE Annual Meeting |
| Publisher | AIChE |
| Pages | 395-400 |
| Number of pages | 6 |
| Volume | 1 |
| ISBN (Electronic) | 9781510858060 |
| Publication status | Published - Jan 1 2017 |
| Event | Catalysis and Reaction Engineering Division 2017 - Core Programming Area at the 2017 AIChE Annual Meeting - Minneapolis, United States Duration: Oct 29 2017 → Nov 3 2017 |
Other
| Other | Catalysis and Reaction Engineering Division 2017 - Core Programming Area at the 2017 AIChE Annual Meeting |
|---|---|
| Country | United States |
| City | Minneapolis |
| Period | 10/29/17 → 11/3/17 |
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ASJC Scopus subject areas
- Nuclear Energy and Engineering
- Catalysis
- Safety, Risk, Reliability and Quality
Cite this
The roles of au clusters and Co-ZSM-5 in the low temperature aerobic selective oxidation of neat ethylbenzene. / Peng, Anyang; Qian, Linpinq; Yan, Ruiyi; Kung, Mayfair C.; Kung, Harold H.
Catalysis and Reaction Engineering Division 2017 - Core Programming Area at the 2017 AIChE Annual Meeting. Vol. 1 AIChE, 2017. p. 395-400.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - The roles of au clusters and Co-ZSM-5 in the low temperature aerobic selective oxidation of neat ethylbenzene
AU - Peng, Anyang
AU - Qian, Linpinq
AU - Yan, Ruiyi
AU - Kung, Mayfair C.
AU - Kung, Harold H
PY - 2017/1/1
Y1 - 2017/1/1
N2 - A synergistic effect between Au and Co has been successfully demonstrated in the selective oxidation of Ethylbenzene. Solubilized Au nanoclusters are initiators different from traditional free radical initiators. Cyclooctene hydroperoxide is most likely to be the mediator between Au and Co. Some oxidation products from c-C8= oxidation can increase the efficiency of peroxide initiator.
AB - A synergistic effect between Au and Co has been successfully demonstrated in the selective oxidation of Ethylbenzene. Solubilized Au nanoclusters are initiators different from traditional free radical initiators. Cyclooctene hydroperoxide is most likely to be the mediator between Au and Co. Some oxidation products from c-C8= oxidation can increase the efficiency of peroxide initiator.
UR - http://www.scopus.com/inward/record.url?scp=85048543952&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85048543952&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:85048543952
VL - 1
SP - 395
EP - 400
BT - Catalysis and Reaction Engineering Division 2017 - Core Programming Area at the 2017 AIChE Annual Meeting
PB - AIChE
ER -