The roles of au clusters and Co-ZSM-5 in the low temperature aerobic selective oxidation of neat ethylbenzene

Anyang Peng; Linpinq Qian; Ruiyi Yan; Mayfair C. Kung; Harold H Kung

The roles of au clusters and Co-ZSM-5 in the low temperature aerobic selective oxidation of neat ethylbenzene

Anyang Peng, Linpinq Qian, Ruiyi Yan, Mayfair C. Kung, Harold H Kung

Northwestern University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

A synergistic effect between Au and Co has been successfully demonstrated in the selective oxidation of Ethylbenzene. Solubilized Au nanoclusters are initiators different from traditional free radical initiators. Cyclooctene hydroperoxide is most likely to be the mediator between Au and Co. Some oxidation products from c-C₈= oxidation can increase the efficiency of peroxide initiator.

Original language	English
Title of host publication	Catalysis and Reaction Engineering Division 2017 - Core Programming Area at the 2017 AIChE Annual Meeting
Publisher	AIChE
Pages	395-400
Number of pages	6
Volume	1
ISBN (Electronic)	9781510858060
Publication status	Published - Jan 1 2017
Event	Catalysis and Reaction Engineering Division 2017 - Core Programming Area at the 2017 AIChE Annual Meeting - Minneapolis, United States Duration: Oct 29 2017 → Nov 3 2017

Other

Other	Catalysis and Reaction Engineering Division 2017 - Core Programming Area at the 2017 AIChE Annual Meeting
Country	United States
City	Minneapolis
Period	10/29/17 → 11/3/17

ASJC Scopus subject areas

Nuclear Energy and Engineering
Catalysis
Safety, Risk, Reliability and Quality

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The roles of au clusters and Co-ZSM-5 in the low temperature aerobic selective oxidation of neat ethylbenzene. / Peng, Anyang; Qian, Linpinq; Yan, Ruiyi; Kung, Mayfair C.; Kung, Harold H.

Catalysis and Reaction Engineering Division 2017 - Core Programming Area at the 2017 AIChE Annual Meeting. Vol. 1 AIChE, 2017. p. 395-400.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Peng, A, Qian, L, Yan, R, Kung, MC & Kung, HH 2017, The roles of au clusters and Co-ZSM-5 in the low temperature aerobic selective oxidation of neat ethylbenzene. in Catalysis and Reaction Engineering Division 2017 - Core Programming Area at the 2017 AIChE Annual Meeting. vol. 1, AIChE, pp. 395-400, Catalysis and Reaction Engineering Division 2017 - Core Programming Area at the 2017 AIChE Annual Meeting, Minneapolis, United States, 10/29/17.

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