The roles of the first and second coordination spheres in the design of molecular catalysts for H2 production and oxidation

M. Rakowski Du Bois; Daniel L. Du Bois

doi:10.1039/b801197b

The roles of the first and second coordination spheres in the design of molecular catalysts for H₂ production and oxidation

M. Rakowski Du Bois, Daniel L. Du Bois

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

466 Citations (Scopus)

Abstract

This tutorial review describes the development of discrete transition metal complexes as electrocatalysts for H₂ formation and oxidation. The approach involves the study of thermodynamic properties of metal hydride intermediates and the design of ligands that incorporate proton relays. The work is inspired by structural features of the H₂ase enzymes and should be of interest to researchers in the areas of biomimetic chemistry as well as catalyst design and hydrogen utilization.

Original language	English
Pages (from-to)	62-72
Number of pages	11
Journal	Chemical Society Reviews
Volume	38
Issue number	1
DOIs	https://doi.org/10.1039/b801197b
Publication status	Published - Dec 16 2009

ASJC Scopus subject areas

Chemistry(all)

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10.1039/b801197b

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