Abstract
The interpretation of activation parameters for electrochemical reactions involving surface-attached or adsorbed reactants is considered and compared with the corresponding experimental quantities for solution-phase reactants. The relation between the experimental activation parameters and the theoretically relevant quantities describing the energetics of heterogeneous electron transfer is summarised; this relationship is shown to be especially straightforward for surface-attached reactants.
| Original language | English |
|---|---|
| Pages (from-to) | 43-51 |
| Number of pages | 9 |
| Journal | Journal of Electroanalytical Chemistry |
| Volume | 145 |
| Issue number | 1 |
| Publication status | Published - Mar 10 1983 |
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ASJC Scopus subject areas
- Electrochemistry
- Analytical Chemistry
- Chemical Engineering(all)
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The significance of electrochemical activation parameters for surface-attached reactants. / Hupp, Joseph T; Weaver, Michael J.
In: Journal of Electroanalytical Chemistry, Vol. 145, No. 1, 10.03.1983, p. 43-51.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - The significance of electrochemical activation parameters for surface-attached reactants
AU - Hupp, Joseph T
AU - Weaver, Michael J.
PY - 1983/3/10
Y1 - 1983/3/10
N2 - The interpretation of activation parameters for electrochemical reactions involving surface-attached or adsorbed reactants is considered and compared with the corresponding experimental quantities for solution-phase reactants. The relation between the experimental activation parameters and the theoretically relevant quantities describing the energetics of heterogeneous electron transfer is summarised; this relationship is shown to be especially straightforward for surface-attached reactants.
AB - The interpretation of activation parameters for electrochemical reactions involving surface-attached or adsorbed reactants is considered and compared with the corresponding experimental quantities for solution-phase reactants. The relation between the experimental activation parameters and the theoretically relevant quantities describing the energetics of heterogeneous electron transfer is summarised; this relationship is shown to be especially straightforward for surface-attached reactants.
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UR - http://www.scopus.com/inward/citedby.url?scp=0020715122&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0020715122
VL - 145
SP - 43
EP - 51
JO - Journal of Electroanalytical Chemistry
JF - Journal of Electroanalytical Chemistry
SN - 1572-6657
IS - 1
ER -