The structural interrelationship between the three polymorphs of Rh2O3 and Rh2S3, Rh2Se3, and Ir2S3

Kenneth R Poeppelmeier, J. M. Newsam, J. M. Brown

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The syntheses of each of the three modifications of rhodium sesquioxide are reviewed and their infrared spectra are described. Models of each of these structures were constructed and manipulated using interactive molecular graphics. Their interrelationship is clearly described and used both to explain the similar features observed in their respective infrared spectra and to predict the occurrence of other discrete structures in the Rh2O3 system. Rhodium sesquisulfide, Rh2S3, is shown to be isostructural with the high pressure modification, II-Rh2O3.

Original languageEnglish
Pages (from-to)68-73
Number of pages6
JournalJournal of Solid State Chemistry
Volume60
Issue number1
DOIs
Publication statusPublished - Nov 1 1985

Fingerprint

Rhodium
Polymorphism
rhodium
Molecular graphics
infrared spectra
Infrared radiation
occurrences
synthesis

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

The structural interrelationship between the three polymorphs of Rh2O3 and Rh2S3, Rh2Se3, and Ir2S3. / Poeppelmeier, Kenneth R; Newsam, J. M.; Brown, J. M.

In: Journal of Solid State Chemistry, Vol. 60, No. 1, 01.11.1985, p. 68-73.

Research output: Contribution to journalArticle

@article{46d74a67fa67417dbfd6d99dedeb9fc8,
title = "The structural interrelationship between the three polymorphs of Rh2O3 and Rh2S3, Rh2Se3, and Ir2S3",
abstract = "The syntheses of each of the three modifications of rhodium sesquioxide are reviewed and their infrared spectra are described. Models of each of these structures were constructed and manipulated using interactive molecular graphics. Their interrelationship is clearly described and used both to explain the similar features observed in their respective infrared spectra and to predict the occurrence of other discrete structures in the Rh2O3 system. Rhodium sesquisulfide, Rh2S3, is shown to be isostructural with the high pressure modification, II-Rh2O3.",
author = "Poeppelmeier, {Kenneth R} and Newsam, {J. M.} and Brown, {J. M.}",
year = "1985",
month = "11",
day = "1",
doi = "10.1016/0022-4596(85)90164-1",
language = "English",
volume = "60",
pages = "68--73",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "Academic Press Inc.",
number = "1",

}

TY - JOUR

T1 - The structural interrelationship between the three polymorphs of Rh2O3 and Rh2S3, Rh2Se3, and Ir2S3

AU - Poeppelmeier, Kenneth R

AU - Newsam, J. M.

AU - Brown, J. M.

PY - 1985/11/1

Y1 - 1985/11/1

N2 - The syntheses of each of the three modifications of rhodium sesquioxide are reviewed and their infrared spectra are described. Models of each of these structures were constructed and manipulated using interactive molecular graphics. Their interrelationship is clearly described and used both to explain the similar features observed in their respective infrared spectra and to predict the occurrence of other discrete structures in the Rh2O3 system. Rhodium sesquisulfide, Rh2S3, is shown to be isostructural with the high pressure modification, II-Rh2O3.

AB - The syntheses of each of the three modifications of rhodium sesquioxide are reviewed and their infrared spectra are described. Models of each of these structures were constructed and manipulated using interactive molecular graphics. Their interrelationship is clearly described and used both to explain the similar features observed in their respective infrared spectra and to predict the occurrence of other discrete structures in the Rh2O3 system. Rhodium sesquisulfide, Rh2S3, is shown to be isostructural with the high pressure modification, II-Rh2O3.

UR - http://www.scopus.com/inward/record.url?scp=0022161637&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0022161637&partnerID=8YFLogxK

U2 - 10.1016/0022-4596(85)90164-1

DO - 10.1016/0022-4596(85)90164-1

M3 - Article

VL - 60

SP - 68

EP - 73

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

IS - 1

ER -