The structure-directing properties of [VOF5]2-

Margaret E. Welk, Alexander J. Norquist, Charlotte L. Stern, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

67 Citations (Scopus)

Abstract

All of the Group 5 anions [MOF5]2- (M = V, Nb, Ta) show the metal distorted from the center of the octahedron to the corner defined by the oxide ion. While [NbOF5]2- and [TaOF5]2- direct coordination through the oxide and trans fluoride ligands, the increase in vanadium oxide bond valence results in coordination through cis fluoride ligands in [VOF5]2-. The structure-directing properties of [VOF5]2- more closely resemble those of the Group 6 anion [MoO2F4]2-.

Original languageEnglish
Pages (from-to)3946-3947
Number of pages2
JournalInorganic Chemistry
Volume39
Issue number18
DOIs
Publication statusPublished - Sep 4 2000

Fingerprint

Oxides
fluorides
anions
Fluorides
ligands
Anions
oxides
vanadium oxides
Ligands
Vanadium
valence
Metals
metals
Ions
ions

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

The structure-directing properties of [VOF5]2- . / Welk, Margaret E.; Norquist, Alexander J.; Stern, Charlotte L.; Poeppelmeier, Kenneth R.

In: Inorganic Chemistry, Vol. 39, No. 18, 04.09.2000, p. 3946-3947.

Research output: Contribution to journalArticle

Welk, Margaret E. ; Norquist, Alexander J. ; Stern, Charlotte L. ; Poeppelmeier, Kenneth R. / The structure-directing properties of [VOF5]2- In: Inorganic Chemistry. 2000 ; Vol. 39, No. 18. pp. 3946-3947.
@article{19321601df7f4dc1b4fb13bdf47b78af,
title = "The structure-directing properties of [VOF5]2-",
abstract = "All of the Group 5 anions [MOF5]2- (M = V, Nb, Ta) show the metal distorted from the center of the octahedron to the corner defined by the oxide ion. While [NbOF5]2- and [TaOF5]2- direct coordination through the oxide and trans fluoride ligands, the increase in vanadium oxide bond valence results in coordination through cis fluoride ligands in [VOF5]2-. The structure-directing properties of [VOF5]2- more closely resemble those of the Group 6 anion [MoO2F4]2-.",
author = "Welk, {Margaret E.} and Norquist, {Alexander J.} and Stern, {Charlotte L.} and Poeppelmeier, {Kenneth R}",
year = "2000",
month = "9",
day = "4",
doi = "10.1021/ic000416d",
language = "English",
volume = "39",
pages = "3946--3947",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "18",

}

TY - JOUR

T1 - The structure-directing properties of [VOF5]2-

AU - Welk, Margaret E.

AU - Norquist, Alexander J.

AU - Stern, Charlotte L.

AU - Poeppelmeier, Kenneth R

PY - 2000/9/4

Y1 - 2000/9/4

N2 - All of the Group 5 anions [MOF5]2- (M = V, Nb, Ta) show the metal distorted from the center of the octahedron to the corner defined by the oxide ion. While [NbOF5]2- and [TaOF5]2- direct coordination through the oxide and trans fluoride ligands, the increase in vanadium oxide bond valence results in coordination through cis fluoride ligands in [VOF5]2-. The structure-directing properties of [VOF5]2- more closely resemble those of the Group 6 anion [MoO2F4]2-.

AB - All of the Group 5 anions [MOF5]2- (M = V, Nb, Ta) show the metal distorted from the center of the octahedron to the corner defined by the oxide ion. While [NbOF5]2- and [TaOF5]2- direct coordination through the oxide and trans fluoride ligands, the increase in vanadium oxide bond valence results in coordination through cis fluoride ligands in [VOF5]2-. The structure-directing properties of [VOF5]2- more closely resemble those of the Group 6 anion [MoO2F4]2-.

UR - http://www.scopus.com/inward/record.url?scp=0034604951&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034604951&partnerID=8YFLogxK

U2 - 10.1021/ic000416d

DO - 10.1021/ic000416d

M3 - Article

C2 - 11198845

AN - SCOPUS:0034604951

VL - 39

SP - 3946

EP - 3947

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 18

ER -