The synthesis and isolation of a metal-substituted bis-silene

Dmitry Bravo-Zhivotovskii, Roman Dobrovetsky, Dmitry Nemirovsky, Victoria Molev, Michael Bendikov, Gregory Molev, Mark Botoshansky, Yitzhak Apeloig

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Si, Si: The reaction of bis(lithiosilyl)mercury with R3Si = iPr3Si with two equivalents of 1-adamantoyl chloride gave, by thermal Brook rearrangement, the first metal-substituted bis-silene. The reaction of bis(lithiosilyl)mercury having smaller tBuMe2Si substituents led to a bis(acylsilyl) mercury, which did not rearrange to the bis-silene. The effect of steric congestion on Brook rearrangement was studied computationally. (Chemical Equation Presented)

Original languageEnglish
Pages (from-to)4343-4345
Number of pages3
JournalAngewandte Chemie - International Edition
Volume47
Issue number23
DOIs
Publication statusPublished - May 26 2008

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Mercury
Metals
Chlorides
Hot Temperature

Keywords

  • Anions
  • Lithium
  • Rearrangements
  • Silenes
  • Structure elucidation

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Bravo-Zhivotovskii, D., Dobrovetsky, R., Nemirovsky, D., Molev, V., Bendikov, M., Molev, G., ... Apeloig, Y. (2008). The synthesis and isolation of a metal-substituted bis-silene. Angewandte Chemie - International Edition, 47(23), 4343-4345. https://doi.org/10.1002/anie.200800973

The synthesis and isolation of a metal-substituted bis-silene. / Bravo-Zhivotovskii, Dmitry; Dobrovetsky, Roman; Nemirovsky, Dmitry; Molev, Victoria; Bendikov, Michael; Molev, Gregory; Botoshansky, Mark; Apeloig, Yitzhak.

In: Angewandte Chemie - International Edition, Vol. 47, No. 23, 26.05.2008, p. 4343-4345.

Research output: Contribution to journalArticle

Bravo-Zhivotovskii, D, Dobrovetsky, R, Nemirovsky, D, Molev, V, Bendikov, M, Molev, G, Botoshansky, M & Apeloig, Y 2008, 'The synthesis and isolation of a metal-substituted bis-silene', Angewandte Chemie - International Edition, vol. 47, no. 23, pp. 4343-4345. https://doi.org/10.1002/anie.200800973
Bravo-Zhivotovskii D, Dobrovetsky R, Nemirovsky D, Molev V, Bendikov M, Molev G et al. The synthesis and isolation of a metal-substituted bis-silene. Angewandte Chemie - International Edition. 2008 May 26;47(23):4343-4345. https://doi.org/10.1002/anie.200800973
Bravo-Zhivotovskii, Dmitry ; Dobrovetsky, Roman ; Nemirovsky, Dmitry ; Molev, Victoria ; Bendikov, Michael ; Molev, Gregory ; Botoshansky, Mark ; Apeloig, Yitzhak. / The synthesis and isolation of a metal-substituted bis-silene. In: Angewandte Chemie - International Edition. 2008 ; Vol. 47, No. 23. pp. 4343-4345.
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