Abstract
A linear Si-Hg-Hg-Si arrangement and a Hg-Hg distance of 265.69 pm are exhibited by the first two-coordinate, dinuclear σ-bonded organomercury(I) compound 1. It was formed unexpectedly in the reaction of two equivalents of the silane (Me3SiMe2Si)3SiH with tBu2Hg. In contrast if the reagents are allowed to react in a 1:1 ratio the expected mercury(II) compound (Me3SiMe2Si)3SiHgtBu is obtained.
| Original language | English |
|---|---|
| Pages (from-to) | 1100-1102 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 38 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - Apr 19 1999 |
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Keywords
- Mercury
- Silicon
ASJC Scopus subject areas
- Chemistry(all)
Cite this
The synthesis and molecular structure of the first two-coordinate, dinuclear σ-bonded mercury(I) RHgHgR compound. / Bravo-Zhivotovskii, Dmitry; Yuzefovich, Michael; Bendikov, Michael; Klinkhammer, Karl; Apeloig, Yitzhak.
In: Angewandte Chemie - International Edition, Vol. 38, No. 8, 19.04.1999, p. 1100-1102.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - The synthesis and molecular structure of the first two-coordinate, dinuclear σ-bonded mercury(I) RHgHgR compound
AU - Bravo-Zhivotovskii, Dmitry
AU - Yuzefovich, Michael
AU - Bendikov, Michael
AU - Klinkhammer, Karl
AU - Apeloig, Yitzhak
PY - 1999/4/19
Y1 - 1999/4/19
N2 - A linear Si-Hg-Hg-Si arrangement and a Hg-Hg distance of 265.69 pm are exhibited by the first two-coordinate, dinuclear σ-bonded organomercury(I) compound 1. It was formed unexpectedly in the reaction of two equivalents of the silane (Me3SiMe2Si)3SiH with tBu2Hg. In contrast if the reagents are allowed to react in a 1:1 ratio the expected mercury(II) compound (Me3SiMe2Si)3SiHgtBu is obtained.
AB - A linear Si-Hg-Hg-Si arrangement and a Hg-Hg distance of 265.69 pm are exhibited by the first two-coordinate, dinuclear σ-bonded organomercury(I) compound 1. It was formed unexpectedly in the reaction of two equivalents of the silane (Me3SiMe2Si)3SiH with tBu2Hg. In contrast if the reagents are allowed to react in a 1:1 ratio the expected mercury(II) compound (Me3SiMe2Si)3SiHgtBu is obtained.
KW - Mercury
KW - Silicon
UR - http://www.scopus.com/inward/record.url?scp=0033583461&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0033583461&partnerID=8YFLogxK
U2 - 10.1002/(SICI)1521-3773(19990419)38:8<1100::AID-ANIE1100>3.0.CO;2-N
DO - 10.1002/(SICI)1521-3773(19990419)38:8<1100::AID-ANIE1100>3.0.CO;2-N
M3 - Article
AN - SCOPUS:0033583461
VL - 38
SP - 1100
EP - 1102
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 8
ER -