The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification

In Soo Kim; Sol Ahn; Nicolaas A. Vermeulen; Thomas E. Webber; Leighanne C. Gallington; Karena W. Chapman; R. Lee Penn; Joseph T. Hupp; Omar K. Farha; Justin M. Notestein; Alex B.F. Martinson

doi:10.1021/jacs.9b10034

The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification

In Soo Kim, Sol Ahn, Nicolaas A. Vermeulen, Thomas E. Webber, Leighanne C. Gallington, Karena W. Chapman, R. Lee Penn, Joseph T. Hupp, Omar K. Farha, Justin M. Notestein, Alex B.F. Martinson

Northwestern University

Research output: Contribution to journal › Article

Abstract

The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure-function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.

Original language	English
Journal	Journal of the American Chemical Society
DOIs	https://doi.org/10.1021/jacs.9b10034
Publication status	Accepted/In press - Jan 1 2019

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ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Cite this

Kim, I. S., Ahn, S., Vermeulen, N. A., Webber, T. E., Gallington, L. C., Chapman, K. W., Penn, R. L., Hupp, J. T., Farha, O. K., Notestein, J. M., & Martinson, A. B. F. (Accepted/In press). The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b10034

The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification. / Kim, In Soo; Ahn, Sol; Vermeulen, Nicolaas A.; Webber, Thomas E.; Gallington, Leighanne C.; Chapman, Karena W.; Penn, R. Lee; Hupp, Joseph T.; Farha, Omar K.; Notestein, Justin M.; Martinson, Alex B.F.

In: Journal of the American Chemical Society, 01.01.2019.

Research output: Contribution to journal › Article

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10.1021/jacs.9b10034