TY - JOUR
T1 - The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification
AU - Kim, In Soo
AU - Ahn, Sol
AU - Vermeulen, Nicolaas A.
AU - Webber, Thomas E.
AU - Gallington, Leighanne C.
AU - Chapman, Karena W.
AU - Penn, R. Lee
AU - Hupp, Joseph T.
AU - Farha, Omar K.
AU - Notestein, Justin M.
AU - Martinson, Alex B.F.
PY - 2020/1/8
Y1 - 2020/1/8
N2 - The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure-function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.
AB - The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure-function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.
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U2 - 10.1021/jacs.9b10034
DO - 10.1021/jacs.9b10034
M3 - Article
C2 - 31851505
AN - SCOPUS:85076973300
VL - 142
SP - 242
EP - 250
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 1
ER -