The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification

In Soo Kim; Sol Ahn; Nicolaas A. Vermeulen; Thomas E. Webber; Leighanne C. Gallington; Karena W. Chapman; R. Lee Penn; Joseph T. Hupp; Omar K. Farha; Justin M. Notestein; Alex B.F. Martinson

doi:10.1021/jacs.9b10034

The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification

In Soo Kim, Sol Ahn, Nicolaas A. Vermeulen, Thomas E. Webber, Leighanne C. Gallington, Karena W. Chapman, R. Lee Penn, Joseph T. Hupp, Omar K. Farha, Justin M. Notestein, Alex B.F. Martinson

Northwestern University

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure-function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.

Original language	English
Pages (from-to)	242-250
Number of pages	9
Journal	Journal of the American Chemical Society
Volume	142
Issue number	1
DOIs	https://doi.org/10.1021/jacs.9b10034
Publication status	Published - Jan 8 2020

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/jacs.9b10034

Fingerprint Dive into the research topics of 'The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification'. Together they form a unique fingerprint.

Cite this

The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification. / Kim, In Soo; Ahn, Sol; Vermeulen, Nicolaas A.; Webber, Thomas E.; Gallington, Leighanne C.; Chapman, Karena W.; Penn, R. Lee; Hupp, Joseph T.; Farha, Omar K.; Notestein, Justin M.; Martinson, Alex B.F.

In: Journal of the American Chemical Society, Vol. 142, No. 1, 08.01.2020, p. 242-250.

Research output: Contribution to journal › Article › peer-review

Kim, In Soo ; Ahn, Sol ; Vermeulen, Nicolaas A. ; Webber, Thomas E. ; Gallington, Leighanne C. ; Chapman, Karena W. ; Penn, R. Lee ; Hupp, Joseph T. ; Farha, Omar K. ; Notestein, Justin M. ; Martinson, Alex B.F. / The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification. In: Journal of the American Chemical Society. 2020 ; Vol. 142, No. 1. pp. 242-250.

@article{52bc8abb657346daac75a3fe1912ab3b,

title = "The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification",

abstract = "The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure-function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.",

author = "Kim, {In Soo} and Sol Ahn and Vermeulen, {Nicolaas A.} and Webber, {Thomas E.} and Gallington, {Leighanne C.} and Chapman, {Karena W.} and Penn, {R. Lee} and Hupp, {Joseph T.} and Farha, {Omar K.} and Notestein, {Justin M.} and Martinson, {Alex B.F.}",

year = "2020",

month = jan,

day = "8",

doi = "10.1021/jacs.9b10034",

language = "English",

volume = "142",

pages = "242--250",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "1",

}

TY - JOUR

T1 - The Synthesis Science of Targeted Vapor-Phase Metal-Organic Framework Postmodification

AU - Kim, In Soo

AU - Ahn, Sol

AU - Vermeulen, Nicolaas A.

AU - Webber, Thomas E.

AU - Gallington, Leighanne C.

AU - Chapman, Karena W.

AU - Penn, R. Lee

AU - Hupp, Joseph T.

AU - Farha, Omar K.

AU - Notestein, Justin M.

AU - Martinson, Alex B.F.

PY - 2020/1/8

Y1 - 2020/1/8

N2 - The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure-function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.

AB - The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure-function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.

UR - http://www.scopus.com/inward/record.url?scp=85076973300&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85076973300&partnerID=8YFLogxK

U2 - 10.1021/jacs.9b10034

DO - 10.1021/jacs.9b10034

M3 - Article

C2 - 31851505

AN - SCOPUS:85076973300

VL - 142

SP - 242

EP - 250

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 1

ER -