Abstract
Quantum-mechanical calculations suggest that silenes are probably not involved as intermediates in the reaction of the trichlorovinylsilane/t-BuLi reagent with alkynes. Instead, the product 7 is obtained via a carbometalation - elimination reaction.
Original language | English |
---|---|
Pages (from-to) | 598-600 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 20 |
Issue number | 4 |
DOIs | |
Publication status | Published - Feb 19 2001 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry