The trichlorovinylsilane/tert-butyllithium reagent - A source for transient silenes?

Thomas Müller; Michael Bendikov; Norbert Auner; Yitzhak Apeloig

doi:10.1021/om000833y

The trichlorovinylsilane/tert-butyllithium reagent - A source for transient silenes?

Thomas Müller, Michael Bendikov, Norbert Auner, Yitzhak Apeloig

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Quantum-mechanical calculations suggest that silenes are probably not involved as intermediates in the reaction of the trichlorovinylsilane/t-BuLi reagent with alkynes. Instead, the product 7 is obtained via a carbometalation - elimination reaction.

Original language	English
Pages (from-to)	598-600
Number of pages	3
Journal	Organometallics
Volume	20
Issue number	4
DOIs	https://doi.org/10.1021/om000833y
Publication status	Published - Feb 19 2001

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om000833y

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@article{a195eca836164a549379f4af3fff1744,

title = "The trichlorovinylsilane/tert-butyllithium reagent - A source for transient silenes?",

abstract = "Quantum-mechanical calculations suggest that silenes are probably not involved as intermediates in the reaction of the trichlorovinylsilane/t-BuLi reagent with alkynes. Instead, the product 7 is obtained via a carbometalation - elimination reaction.",

author = "Thomas M{\"u}ller and Michael Bendikov and Norbert Auner and Yitzhak Apeloig",

year = "2001",

month = feb,

day = "19",

doi = "10.1021/om000833y",

language = "English",

volume = "20",

pages = "598--600",

journal = "Organometallics",

issn = "0276-7333",