Quantum-mechanical calculations suggest that silenes are probably not involved as intermediates in the reaction of the trichlorovinylsilane/t-BuLi reagent with alkynes. Instead, the product 7 is obtained via a carbometalation - elimination reaction.
|Number of pages||3|
|Publication status||Published - Feb 19 2001|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry