Abstract
Quantum-mechanical calculations suggest that silenes are probably not involved as intermediates in the reaction of the trichlorovinylsilane/t-BuLi reagent with alkynes. Instead, the product 7 is obtained via a carbometalation - elimination reaction.
| Original language | English |
|---|---|
| Pages (from-to) | 598-600 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 20 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Feb 19 2001 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Cite this
Müller, T., Bendikov, M., Auner, N., & Apeloig, Y. (2001). The trichlorovinylsilane/tert-butyllithium reagent - A source for transient silenes? Organometallics, 20(4), 598-600. https://doi.org/10.1021/om000833y