The trichlorovinylsilane/tert-butyllithium reagent - A source for transient silenes?

Thomas Müller, Michael Bendikov, Norbert Auner, Yitzhak Apeloig

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Quantum-mechanical calculations suggest that silenes are probably not involved as intermediates in the reaction of the trichlorovinylsilane/t-BuLi reagent with alkynes. Instead, the product 7 is obtained via a carbometalation - elimination reaction.

Original languageEnglish
Pages (from-to)598-600
Number of pages3
JournalOrganometallics
Volume20
Issue number4
Publication statusPublished - Feb 19 2001

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Alkynes
reagents
alkynes
elimination
products
n-butyllithium
trichlorovinylsilane

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

The trichlorovinylsilane/tert-butyllithium reagent - A source for transient silenes? / Müller, Thomas; Bendikov, Michael; Auner, Norbert; Apeloig, Yitzhak.

In: Organometallics, Vol. 20, No. 4, 19.02.2001, p. 598-600.

Research output: Contribution to journalArticle

Müller, Thomas ; Bendikov, Michael ; Auner, Norbert ; Apeloig, Yitzhak. / The trichlorovinylsilane/tert-butyllithium reagent - A source for transient silenes?. In: Organometallics. 2001 ; Vol. 20, No. 4. pp. 598-600.
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