Abstract
Quantum-mechanical calculations suggest that silenes are probably not involved as intermediates in the reaction of the trichlorovinylsilane/t-BuLi reagent with alkynes. Instead, the product 7 is obtained via a carbometalation - elimination reaction.
| Original language | English |
|---|---|
| Pages (from-to) | 598-600 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 20 |
| Issue number | 4 |
| Publication status | Published - Feb 19 2001 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
Cite this
The trichlorovinylsilane/tert-butyllithium reagent - A source for transient silenes? / Müller, Thomas; Bendikov, Michael; Auner, Norbert; Apeloig, Yitzhak.
In: Organometallics, Vol. 20, No. 4, 19.02.2001, p. 598-600.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - The trichlorovinylsilane/tert-butyllithium reagent - A source for transient silenes?
AU - Müller, Thomas
AU - Bendikov, Michael
AU - Auner, Norbert
AU - Apeloig, Yitzhak
PY - 2001/2/19
Y1 - 2001/2/19
N2 - Quantum-mechanical calculations suggest that silenes are probably not involved as intermediates in the reaction of the trichlorovinylsilane/t-BuLi reagent with alkynes. Instead, the product 7 is obtained via a carbometalation - elimination reaction.
AB - Quantum-mechanical calculations suggest that silenes are probably not involved as intermediates in the reaction of the trichlorovinylsilane/t-BuLi reagent with alkynes. Instead, the product 7 is obtained via a carbometalation - elimination reaction.
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UR - http://www.scopus.com/inward/citedby.url?scp=0035249876&partnerID=8YFLogxK
M3 - Article
VL - 20
SP - 598
EP - 600
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 4
ER -