Abstract
A quantum mechanical theory for polyatomic molecules undergoing bimolecular reactions is presented which allows prediction of the vibrational excitation of the products as a function of (a) the incident translational energy, (b) the curvature of the reaction path, (c) the frequency changes for degrees of freedom perpendicular to the reaction coordinate, and (d) the position of the saddle point of the potential hypersurface.
| Original language | English |
|---|---|
| Pages (from-to) | 2769-2776 |
| Number of pages | 8 |
| Journal | Journal of Chemical Physics |
| Volume | 57 |
| Issue number | 7 |
| Publication status | Published - 1972 |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
Cite this
Theory of translational-vibrational energy transfer for reactive collisions. / Fischer, Sighart F.; Ratner, Mark A.
In: Journal of Chemical Physics, Vol. 57, No. 7, 1972, p. 2769-2776.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Theory of translational-vibrational energy transfer for reactive collisions
AU - Fischer, Sighart F.
AU - Ratner, Mark A
PY - 1972
Y1 - 1972
N2 - A quantum mechanical theory for polyatomic molecules undergoing bimolecular reactions is presented which allows prediction of the vibrational excitation of the products as a function of (a) the incident translational energy, (b) the curvature of the reaction path, (c) the frequency changes for degrees of freedom perpendicular to the reaction coordinate, and (d) the position of the saddle point of the potential hypersurface.
AB - A quantum mechanical theory for polyatomic molecules undergoing bimolecular reactions is presented which allows prediction of the vibrational excitation of the products as a function of (a) the incident translational energy, (b) the curvature of the reaction path, (c) the frequency changes for degrees of freedom perpendicular to the reaction coordinate, and (d) the position of the saddle point of the potential hypersurface.
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UR - http://www.scopus.com/inward/citedby.url?scp=2742530344&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:2742530344
VL - 57
SP - 2769
EP - 2776
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 7
ER -