Thermodynamic studies of the addition of N2, C2H4, and alkynes to [Rh(PiPr3)2Cl]2

Kun Wang, Alan S Goldman, Chunbang Li, Steven P. Nolan

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

[Rh(PiPr3)2Cl]2 reacts with various small molecules L′ to give complexes Rh(PiPr3)2ClL′. The enthalpy of this reaction has been determined calorimetrically and/or by equilibrium methods for L′ = N2, C2H4, diphenylacetylene, and 2-butyne. These values, in combination with the previously determined lower limit for the [Rh(PiPr3)2Cl]2 bridge strength, afford lower limits of the Rh-L′ BDE's; the lower limits are probably only slightly less than the actual BDE's.

Original languageEnglish
Pages (from-to)4010-4013
Number of pages4
JournalOrganometallics
Volume14
Issue number8
Publication statusPublished - 1995

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Alkynes
alkynes
Enthalpy
Thermodynamics
thermodynamics
Molecules
equilibrium methods
enthalpy
biphenylacetylene
molecules

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Thermodynamic studies of the addition of N2, C2H4, and alkynes to [Rh(PiPr3)2Cl]2 . / Wang, Kun; Goldman, Alan S; Li, Chunbang; Nolan, Steven P.

In: Organometallics, Vol. 14, No. 8, 1995, p. 4010-4013.

Research output: Contribution to journalArticle

Wang, Kun ; Goldman, Alan S ; Li, Chunbang ; Nolan, Steven P. / Thermodynamic studies of the addition of N2, C2H4, and alkynes to [Rh(PiPr3)2Cl]2 . In: Organometallics. 1995 ; Vol. 14, No. 8. pp. 4010-4013.
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