Abstract
The electrochemical instability of semiconductors in aqueous electrolytes has impeded the development of robust sunlight-driven water-splitting systems. We review the use of protective thin films to improve the electrochemical stability of otherwise unstable semiconductor photoelectrodes (e.g., Si and GaAs). We first discuss the origins of instability and various strategies for achieving stable and functional photoelectrosynthetic interfaces. We then focus specifically on the use of thin protective films on photoanodes and photocathodes for photosynthetic reactions that include oxygen evolution, halide oxidation, and hydrogen evolution. Finally, we provide an outlook for the future development of thin-layer protection strategies to enable semiconductor-based solar-driven fuel production.
| Original language | English |
|---|---|
| Pages (from-to) | 24201-24228 |
| Number of pages | 28 |
| Journal | Journal of Physical Chemistry C |
| Volume | 119 |
| Issue number | 43 |
| DOIs | |
| Publication status | Published - Oct 29 2015 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Electronic, Optical and Magnetic Materials
- Surfaces, Coatings and Films
- Energy(all)
Cite this
Thin-Film Materials for the Protection of Semiconducting Photoelectrodes in Solar-Fuel Generators. / Hu, Shu; Lewis, Nathan S; Ager, Joel W.; Yang, Jinhui; McKone, James R.; Strandwitz, Nicholas C.
In: Journal of Physical Chemistry C, Vol. 119, No. 43, 29.10.2015, p. 24201-24228.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Thin-Film Materials for the Protection of Semiconducting Photoelectrodes in Solar-Fuel Generators
AU - Hu, Shu
AU - Lewis, Nathan S
AU - Ager, Joel W.
AU - Yang, Jinhui
AU - McKone, James R.
AU - Strandwitz, Nicholas C.
PY - 2015/10/29
Y1 - 2015/10/29
N2 - The electrochemical instability of semiconductors in aqueous electrolytes has impeded the development of robust sunlight-driven water-splitting systems. We review the use of protective thin films to improve the electrochemical stability of otherwise unstable semiconductor photoelectrodes (e.g., Si and GaAs). We first discuss the origins of instability and various strategies for achieving stable and functional photoelectrosynthetic interfaces. We then focus specifically on the use of thin protective films on photoanodes and photocathodes for photosynthetic reactions that include oxygen evolution, halide oxidation, and hydrogen evolution. Finally, we provide an outlook for the future development of thin-layer protection strategies to enable semiconductor-based solar-driven fuel production.
AB - The electrochemical instability of semiconductors in aqueous electrolytes has impeded the development of robust sunlight-driven water-splitting systems. We review the use of protective thin films to improve the electrochemical stability of otherwise unstable semiconductor photoelectrodes (e.g., Si and GaAs). We first discuss the origins of instability and various strategies for achieving stable and functional photoelectrosynthetic interfaces. We then focus specifically on the use of thin protective films on photoanodes and photocathodes for photosynthetic reactions that include oxygen evolution, halide oxidation, and hydrogen evolution. Finally, we provide an outlook for the future development of thin-layer protection strategies to enable semiconductor-based solar-driven fuel production.
UR - http://www.scopus.com/inward/record.url?scp=84946105911&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84946105911&partnerID=8YFLogxK
U2 - 10.1021/acs.jpcc.5b05976
DO - 10.1021/acs.jpcc.5b05976
M3 - Article
AN - SCOPUS:84946105911
VL - 119
SP - 24201
EP - 24228
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 43
ER -