Thin-Film Materials for the Protection of Semiconducting Photoelectrodes in Solar-Fuel Generators

Shu Hu, Nathan S Lewis, Joel W. Ager, Jinhui Yang, James R. McKone, Nicholas C. Strandwitz

Research output: Contribution to journalArticle

127 Citations (Scopus)

Abstract

The electrochemical instability of semiconductors in aqueous electrolytes has impeded the development of robust sunlight-driven water-splitting systems. We review the use of protective thin films to improve the electrochemical stability of otherwise unstable semiconductor photoelectrodes (e.g., Si and GaAs). We first discuss the origins of instability and various strategies for achieving stable and functional photoelectrosynthetic interfaces. We then focus specifically on the use of thin protective films on photoanodes and photocathodes for photosynthetic reactions that include oxygen evolution, halide oxidation, and hydrogen evolution. Finally, we provide an outlook for the future development of thin-layer protection strategies to enable semiconductor-based solar-driven fuel production.

Original languageEnglish
Pages (from-to)24201-24228
Number of pages28
JournalJournal of Physical Chemistry C
Volume119
Issue number43
DOIs
Publication statusPublished - Oct 29 2015

Fingerprint

generators
Semiconductor materials
Thin films
thin films
fuel production
Plasma stability
Photocathodes
water splitting
Protective coatings
photocathodes
sunlight
Electrolytes
halides
Hydrogen
electrolytes
Oxygen
Oxidation
oxidation
Water
oxygen

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Thin-Film Materials for the Protection of Semiconducting Photoelectrodes in Solar-Fuel Generators. / Hu, Shu; Lewis, Nathan S; Ager, Joel W.; Yang, Jinhui; McKone, James R.; Strandwitz, Nicholas C.

In: Journal of Physical Chemistry C, Vol. 119, No. 43, 29.10.2015, p. 24201-24228.

Research output: Contribution to journalArticle

Hu, Shu ; Lewis, Nathan S ; Ager, Joel W. ; Yang, Jinhui ; McKone, James R. ; Strandwitz, Nicholas C. / Thin-Film Materials for the Protection of Semiconducting Photoelectrodes in Solar-Fuel Generators. In: Journal of Physical Chemistry C. 2015 ; Vol. 119, No. 43. pp. 24201-24228.
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