Time-resolved Fourier transform infrared study of the photodissociation of 1,1-difluoroethene at 193 nm

Gregory E. Hall, James Muckerman, Jack M. Preses, Ralph E. Weston, George W. Flynn, Avigdor Persky

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

In the experiments described in this work, the fragmentation of 1,1-difluoroethene, using one-photon UV excitation at 193 nm was studied. The vibrational and rotational population distributions of the HF product were determined using time-resolved Fourier transform infrared. As the CH2CF2 molecule can only from HF in an α,β-dissociation, the ambiguity that existed in the case of others species, such as CF3CF2H, was eliminated.

Original languageEnglish
Pages (from-to)3679-3687
Number of pages9
JournalJournal of Chemical Physics
Volume101
Issue number5
Publication statusPublished - Sep 1 1994

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Population distribution
Photodissociation
photodissociation
ambiguity
Fourier transforms
fragmentation
Photons
dissociation
Infrared radiation
Molecules
photons
products
excitation
molecules
Experiments

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Hall, G. E., Muckerman, J., Preses, J. M., Weston, R. E., Flynn, G. W., & Persky, A. (1994). Time-resolved Fourier transform infrared study of the photodissociation of 1,1-difluoroethene at 193 nm. Journal of Chemical Physics, 101(5), 3679-3687.

Time-resolved Fourier transform infrared study of the photodissociation of 1,1-difluoroethene at 193 nm. / Hall, Gregory E.; Muckerman, James; Preses, Jack M.; Weston, Ralph E.; Flynn, George W.; Persky, Avigdor.

In: Journal of Chemical Physics, Vol. 101, No. 5, 01.09.1994, p. 3679-3687.

Research output: Contribution to journalArticle

Hall, GE, Muckerman, J, Preses, JM, Weston, RE, Flynn, GW & Persky, A 1994, 'Time-resolved Fourier transform infrared study of the photodissociation of 1,1-difluoroethene at 193 nm', Journal of Chemical Physics, vol. 101, no. 5, pp. 3679-3687.
Hall, Gregory E. ; Muckerman, James ; Preses, Jack M. ; Weston, Ralph E. ; Flynn, George W. ; Persky, Avigdor. / Time-resolved Fourier transform infrared study of the photodissociation of 1,1-difluoroethene at 193 nm. In: Journal of Chemical Physics. 1994 ; Vol. 101, No. 5. pp. 3679-3687.
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