Tin-119m Mossbauer and X-Ray Photoelectron (ESCA) Studies of Tin Oxidation State and Bonding in Base-Dialkyltin Pentacarbonylehromium and Tetracarbonyliron Complexes

G. W. Grynkewich, T. J. Marks, B. Y.K. Ho, D. L. Tomaja, J. J. Zuckerman

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

119mSn Mossbauer, 119Sn-1 H three-bond nmr coupling constants, and Sn 3d5/2 ESCA electron binding energy data for the compounds (t-C4H9)2SnM(CO)x. B, where for M = Fe, x = 4 and B = DMSO and pyridine and for M = Cr, x = 5 and B = THF, DMSO, and pyridine, favor a tin(IV) formulation. The Mossbauer QS values for M = Cr compounds (3. 4-4. 1 mm/sec) are the largest thus far recorded for four-coordinated organotin compounds. Explanations based upon ylide structures are proposed.

Original languageEnglish
Pages (from-to)2522-2525
Number of pages4
JournalInorganic Chemistry
Volume12
Issue number11
DOIs
Publication statusPublished - Nov 1 1973

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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