TiO2-ZnS Cascade Electron Transport Layer for Efficient Formamidinium Tin Iodide Perovskite Solar Cells

Weijun Ke, Constantinos C. Stoumpos, Jenna Leigh Logsdon, Michael R Wasielewski, Yanfa Yan, Guojia Fang, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

79 Citations (Scopus)

Abstract

Achieving high open-circuit voltage (Voc) for tin-based perovskite solar cells is challenging. Here, we demonstrate that a ZnS interfacial layer can improve the Voc and photovoltaic performance of formamidinium tin iodide (FASnI3) perovskite solar cells. The TiO2-ZnS electron transporting layer (ETL) with cascade conduction band structure can effectively reduce the interfacial charge recombination and facilitate electron transfer. Our best-performing FASnI3 perovskite solar cell using the cascaded TiO2-ZnS ETL has achieved a power conversion efficiency of 5.27%, with a higher Voc of 0.380 V, a short-circuit current density of 23.09 mA cm-2, and a fill factor of 60.01%. The cascade structure is further validated with a TiO2-CdS ETL. Our results suggest a new approach for further improving the performance of tin-based perovskite solar cells with a higher Voc.

Original languageEnglish
Pages (from-to)14998-15003
Number of pages6
JournalJournal of the American Chemical Society
Volume138
Issue number45
DOIs
Publication statusPublished - Nov 16 2016

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Tin
Iodides
Electron Transport
Electrons
Open circuit voltage
Conduction bands
Short circuit currents
Band structure
Genetic Recombination
Conversion efficiency
Current density
formamidine
Perovskite solar cells
perovskite

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

TiO2-ZnS Cascade Electron Transport Layer for Efficient Formamidinium Tin Iodide Perovskite Solar Cells. / Ke, Weijun; Stoumpos, Constantinos C.; Logsdon, Jenna Leigh; Wasielewski, Michael R; Yan, Yanfa; Fang, Guojia; Kanatzidis, Mercouri G.

In: Journal of the American Chemical Society, Vol. 138, No. 45, 16.11.2016, p. 14998-15003.

Research output: Contribution to journalArticle

Ke, Weijun ; Stoumpos, Constantinos C. ; Logsdon, Jenna Leigh ; Wasielewski, Michael R ; Yan, Yanfa ; Fang, Guojia ; Kanatzidis, Mercouri G. / TiO2-ZnS Cascade Electron Transport Layer for Efficient Formamidinium Tin Iodide Perovskite Solar Cells. In: Journal of the American Chemical Society. 2016 ; Vol. 138, No. 45. pp. 14998-15003.
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AU - Yan, Yanfa

AU - Fang, Guojia

AU - Kanatzidis, Mercouri G

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