Abstract
A single crystal of Ba4B11O20F (BBOF) with dimensions of 20 × 17 × 12 mm3 was successfully grown using the top-seeded solution growth method. BBOF melts incongruently; as such several flux systems are discussed. The morphologies and growth habits of BBOF crystals grown with differently oriented seeds, [100], [010], and [001], were investigated. Using the [010]-oriented seed, the single crystal exhibits (200) and (010) faces. Rocking curve measurements indicate that the single crystal is of high quality with a full width at half-maximum (fwhm) of 0.017° (61 arcsec) from the (010) reflection. The transmission spectrum and the refractive indices from the UV to the near-infrared region are reported. BBOF is transparent from 190-2500 nm and exhibits a birefringence of 0.0146 at 1064 nm. The type-I phase matching wavelength region was determined based on the fitted Sellmeier equations to the refractive index data. BBOF is type-I phase-matchable with fundamental (second-harmonic) wavelength ranges from 1049-2348 nm (524.5-1174 nm). In addition, the nonlinear optical coefficients for BBOF were measured using the Maker fringe method. For BBOF at 1064 nm, d31 = 1.57 pm/V, d32 = 0.27 pm/V, and d33 = 0.46 pm/V.
| Original language | English |
|---|---|
| Pages (from-to) | 1404-1410 |
| Number of pages | 7 |
| Journal | Crystal Growth and Design |
| Volume | 17 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Mar 1 2017 |
Fingerprint
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Top-Seeded Solution Crystal Growth and Linear and Nonlinear Optical Properties of Ba4B11O20F. / Wu, Hongping; Yu, Hongwei; Zhang, Weiguo; Cantwell, Jacqueline; Poeppelmeier, Kenneth R; Pan, Shilie; Halasyamani, P. Shiv.
In: Crystal Growth and Design, Vol. 17, No. 3, 01.03.2017, p. 1404-1410.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Top-Seeded Solution Crystal Growth and Linear and Nonlinear Optical Properties of Ba4B11O20F
AU - Wu, Hongping
AU - Yu, Hongwei
AU - Zhang, Weiguo
AU - Cantwell, Jacqueline
AU - Poeppelmeier, Kenneth R
AU - Pan, Shilie
AU - Halasyamani, P. Shiv
PY - 2017/3/1
Y1 - 2017/3/1
N2 - A single crystal of Ba4B11O20F (BBOF) with dimensions of 20 × 17 × 12 mm3 was successfully grown using the top-seeded solution growth method. BBOF melts incongruently; as such several flux systems are discussed. The morphologies and growth habits of BBOF crystals grown with differently oriented seeds, [100], [010], and [001], were investigated. Using the [010]-oriented seed, the single crystal exhibits (200) and (010) faces. Rocking curve measurements indicate that the single crystal is of high quality with a full width at half-maximum (fwhm) of 0.017° (61 arcsec) from the (010) reflection. The transmission spectrum and the refractive indices from the UV to the near-infrared region are reported. BBOF is transparent from 190-2500 nm and exhibits a birefringence of 0.0146 at 1064 nm. The type-I phase matching wavelength region was determined based on the fitted Sellmeier equations to the refractive index data. BBOF is type-I phase-matchable with fundamental (second-harmonic) wavelength ranges from 1049-2348 nm (524.5-1174 nm). In addition, the nonlinear optical coefficients for BBOF were measured using the Maker fringe method. For BBOF at 1064 nm, d31 = 1.57 pm/V, d32 = 0.27 pm/V, and d33 = 0.46 pm/V.
AB - A single crystal of Ba4B11O20F (BBOF) with dimensions of 20 × 17 × 12 mm3 was successfully grown using the top-seeded solution growth method. BBOF melts incongruently; as such several flux systems are discussed. The morphologies and growth habits of BBOF crystals grown with differently oriented seeds, [100], [010], and [001], were investigated. Using the [010]-oriented seed, the single crystal exhibits (200) and (010) faces. Rocking curve measurements indicate that the single crystal is of high quality with a full width at half-maximum (fwhm) of 0.017° (61 arcsec) from the (010) reflection. The transmission spectrum and the refractive indices from the UV to the near-infrared region are reported. BBOF is transparent from 190-2500 nm and exhibits a birefringence of 0.0146 at 1064 nm. The type-I phase matching wavelength region was determined based on the fitted Sellmeier equations to the refractive index data. BBOF is type-I phase-matchable with fundamental (second-harmonic) wavelength ranges from 1049-2348 nm (524.5-1174 nm). In addition, the nonlinear optical coefficients for BBOF were measured using the Maker fringe method. For BBOF at 1064 nm, d31 = 1.57 pm/V, d32 = 0.27 pm/V, and d33 = 0.46 pm/V.
UR - http://www.scopus.com/inward/record.url?scp=85014181537&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85014181537&partnerID=8YFLogxK
U2 - 10.1021/acs.cgd.6b01857
DO - 10.1021/acs.cgd.6b01857
M3 - Article
AN - SCOPUS:85014181537
VL - 17
SP - 1404
EP - 1410
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 3
ER -