TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE.

X. Zhou, Tobin J Marks, S. H. Carr

Research output: Chapter in Book/Report/Conference proceedingConference contribution

3 Citations (Scopus)

Abstract

The cofacially linked Group IV poly (phthalocyaninatometalloxane) macromolecules, left bracket M(Pc)O right bracket //n, M equals Si, Ge, Sn are precursors for a broad new class of environmentally stable and processable electrically conductive polymers. This contribution presents mechanistic information on the Ge(Pc)(OH)//2 polymerization by TEM (transmission electron microscopy) and DSC (differential scanning calorimetry). It reports on direct imaging of the left bracket Ge(Pc)O right bracket //n lattice (the first for a conductive polymer), new structural information on Ge(Pc)(OH)//2 evidence for the topotacticity of the polymerization process, and a reasonable mechanism for the polymerization.

Original languageEnglish
Title of host publicationPolymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material
PublisherACS
Pages651-654
Number of pages4
Volume51
Publication statusPublished - 1984

Fingerprint

Polymerization
Polymers
Macromolecules
Differential scanning calorimetry
Transmission electron microscopy
Imaging techniques

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Zhou, X., Marks, T. J., & Carr, S. H. (1984). TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE. In Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material (Vol. 51, pp. 651-654). ACS.

TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE. / Zhou, X.; Marks, Tobin J; Carr, S. H.

Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material. Vol. 51 ACS, 1984. p. 651-654.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Zhou, X, Marks, TJ & Carr, SH 1984, TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE. in Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material. vol. 51, ACS, pp. 651-654.
Zhou X, Marks TJ, Carr SH. TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE. In Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material. Vol. 51. ACS. 1984. p. 651-654
Zhou, X. ; Marks, Tobin J ; Carr, S. H. / TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE. Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material. Vol. 51 ACS, 1984. pp. 651-654
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