Toward atomically-precise synthesis of supported bimetallic nanoparticles using atomic layer deposition

Junling Lu, Ke Bin Low, Yu Lei, Joseph A. Libera, Alan Nicholls, Peter C Stair, Jeffrey W. Elam

Research output: Contribution to journalArticle

96 Citations (Scopus)

Abstract

Multi-metallic nanoparticles constitute a new class of materials offering the opportunity to tune the properties via the composition, atomic ordering and size. In particular, supported bimetallic nanoparticles have generated intense interest in catalysis and electrocatalysis. However, traditional synthesis methods often lack precise control, yielding a mixture of monometallic and bimetallic particles with various compositions. Here we report a general strategy for synthesizing supported bimetallic nanoparticles by atomic layer deposition, where monometallic nanoparticle formation is avoided by selectively growing the secondary metal on the primary metal nanoparticle but not on the support; meanwhile, the size, composition and structure of the bimetallic nanoparticles are precisely controlled by tailoring the precursor pulse sequence. Such exquisite control is clearly demonstrated through in situ Fourier transform infrared spectroscopy of CO chemisorption by mapping the gradual atomic-scale evolution in the surface composition, and further confirmed using aberration-corrected scanning transmission electron microscopy.

Original languageEnglish
Article number3264
JournalNature Communications
Volume5
DOIs
Publication statusPublished - Feb 10 2014

Fingerprint

Atomic layer deposition
atomic layer epitaxy
Nanoparticles
Metal Nanoparticles
nanoparticles
synthesis
Scanning Transmission Electron Microscopy
Chemical analysis
Fourier Transform Infrared Spectroscopy
Carbon Monoxide
Electrocatalysis
Catalysis
Metal nanoparticles
Chemisorption
Aberrations
Surface structure
Metals
metals
chemisorption
catalysis

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)
  • Chemistry(all)
  • Physics and Astronomy(all)

Cite this

Toward atomically-precise synthesis of supported bimetallic nanoparticles using atomic layer deposition. / Lu, Junling; Low, Ke Bin; Lei, Yu; Libera, Joseph A.; Nicholls, Alan; Stair, Peter C; Elam, Jeffrey W.

In: Nature Communications, Vol. 5, 3264, 10.02.2014.

Research output: Contribution to journalArticle

Lu, Junling ; Low, Ke Bin ; Lei, Yu ; Libera, Joseph A. ; Nicholls, Alan ; Stair, Peter C ; Elam, Jeffrey W. / Toward atomically-precise synthesis of supported bimetallic nanoparticles using atomic layer deposition. In: Nature Communications. 2014 ; Vol. 5.
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