Towards hydroxamic acid linked zirconium metal-organic frameworks

Carla F. Pereira, Ashlee J. Howarth, Nicolaas A. Vermeulen, Filipe A. Almeida Paz, João P.C. Tomé, Joseph T. Hupp, Omar K. Farha

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Solvent-assisted linker exchange (SALE) is performed on the Zr-based metal-organic framework (MOF), UiO-66, to exchange benzene-1,4-dicarboxylate with benzene-1,4-dihydroxamate linkers. Characterization of the material before and after SALE is performed using powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), nitrogen adsorption, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and thermogravimetric analysis (TGA). The stability of the parent and daughter material is evaluated at pH 1 and 12 and the structural integrity evaluated by PXRD, mass balance and porosity measurements.

Original languageEnglish
Pages (from-to)1194-1199
Number of pages6
JournalMaterials Chemistry Frontiers
Volume1
Issue number6
DOIs
Publication statusPublished - Jun 2017

ASJC Scopus subject areas

  • Materials Science(all)
  • Materials Chemistry

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    Pereira, C. F., Howarth, A. J., Vermeulen, N. A., Almeida Paz, F. A., Tomé, J. P. C., Hupp, J. T., & Farha, O. K. (2017). Towards hydroxamic acid linked zirconium metal-organic frameworks. Materials Chemistry Frontiers, 1(6), 1194-1199. https://doi.org/10.1039/c6qm00364h