Tröger's-base-derived infinite co-ordination polymer microparticles

You Moon Jeon; Gerasimos S. Armatas; Dongwoo Kim; Mercouri G. Kanatzidis; Chad A. Mirkin

doi:10.1002/smll.200801160

Tröger's-base-derived infinite co-ordination polymer microparticles

You Moon Jeon, Gerasimos S. Armatas, Dongwoo Kim, Mercouri G. Kanatzidis, Chad A. Mirkin

Northwestern University

Research output: Contribution to journal › Article › peer-review

88 Citations (Scopus)

Abstract

A study was conducted to demonstrate a new type of ligand based upon Tröger's base derived infinite co-ordination polymer (ICP) microparticles. The study that the the ICPs were generated, along with zinc (Zn²⁺) ions as interconnecting nodes. It was observed that the ICPs exhibited selective H₂ adsorption properties in the presence of N₂. A scanning electron microscopy (SEM) investigation of the structures that led to the formation of ICPs, provided significant information about the way novel ICP forms. Tröger's base was chosen for conducting the investigation, as its ring shape led to an interconnected co-ordination polymer, having transition metal ion nodes, with the appropriate co-ordinating functionalities (CO ₂H). The Tröger's base-derived ligands were synthesized in two steps to generate ICPs.

Original language	English
Pages (from-to)	46-50
Number of pages	5
Journal	Small
Volume	5
Issue number	1
DOIs	https://doi.org/10.1002/smll.200801160
Publication status	Published - Jan 2009

Keywords

Gas separation
Hydrogen storage
Microparticles
Porous materials
Tröger's base

ASJC Scopus subject areas

Biotechnology
Biomaterials
Chemistry(all)
Materials Science(all)

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abstract = "A study was conducted to demonstrate a new type of ligand based upon Tr{\"o}ger's base derived infinite co-ordination polymer (ICP) microparticles. The study that the the ICPs were generated, along with zinc (Zn2+) ions as interconnecting nodes. It was observed that the ICPs exhibited selective H2 adsorption properties in the presence of N2. A scanning electron microscopy (SEM) investigation of the structures that led to the formation of ICPs, provided significant information about the way novel ICP forms. Tr{\"o}ger's base was chosen for conducting the investigation, as its ring shape led to an interconnected co-ordination polymer, having transition metal ion nodes, with the appropriate co-ordinating functionalities (CO 2H). The Tr{\"o}ger's base-derived ligands were synthesized in two steps to generate ICPs.",

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