Abstract
A study was conducted to demonstrate a new type of ligand based upon Tröger's base derived infinite co-ordination polymer (ICP) microparticles. The study that the the ICPs were generated, along with zinc (Zn2+) ions as interconnecting nodes. It was observed that the ICPs exhibited selective H2 adsorption properties in the presence of N2. A scanning electron microscopy (SEM) investigation of the structures that led to the formation of ICPs, provided significant information about the way novel ICP forms. Tröger's base was chosen for conducting the investigation, as its ring shape led to an interconnected co-ordination polymer, having transition metal ion nodes, with the appropriate co-ordinating functionalities (CO 2H). The Tröger's base-derived ligands were synthesized in two steps to generate ICPs.
| Original language | English |
|---|---|
| Pages (from-to) | 46-50 |
| Number of pages | 5 |
| Journal | Small |
| Volume | 5 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 2009 |
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Keywords
- Gas separation
- Hydrogen storage
- Microparticles
- Porous materials
- Tröger's base
ASJC Scopus subject areas
- Biomaterials
- Engineering (miscellaneous)
- Biotechnology
- Medicine(all)
Cite this
Tröger's-base-derived infinite co-ordination polymer microparticles. / Jeon, You Moon; Armatas, Gerasimos S.; Kim, Dongwoo; Kanatzidis, Mercouri G; Mirkin, Chad A.
In: Small, Vol. 5, No. 1, 01.2009, p. 46-50.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Tröger's-base-derived infinite co-ordination polymer microparticles
AU - Jeon, You Moon
AU - Armatas, Gerasimos S.
AU - Kim, Dongwoo
AU - Kanatzidis, Mercouri G
AU - Mirkin, Chad A.
PY - 2009/1
Y1 - 2009/1
N2 - A study was conducted to demonstrate a new type of ligand based upon Tröger's base derived infinite co-ordination polymer (ICP) microparticles. The study that the the ICPs were generated, along with zinc (Zn2+) ions as interconnecting nodes. It was observed that the ICPs exhibited selective H2 adsorption properties in the presence of N2. A scanning electron microscopy (SEM) investigation of the structures that led to the formation of ICPs, provided significant information about the way novel ICP forms. Tröger's base was chosen for conducting the investigation, as its ring shape led to an interconnected co-ordination polymer, having transition metal ion nodes, with the appropriate co-ordinating functionalities (CO 2H). The Tröger's base-derived ligands were synthesized in two steps to generate ICPs.
AB - A study was conducted to demonstrate a new type of ligand based upon Tröger's base derived infinite co-ordination polymer (ICP) microparticles. The study that the the ICPs were generated, along with zinc (Zn2+) ions as interconnecting nodes. It was observed that the ICPs exhibited selective H2 adsorption properties in the presence of N2. A scanning electron microscopy (SEM) investigation of the structures that led to the formation of ICPs, provided significant information about the way novel ICP forms. Tröger's base was chosen for conducting the investigation, as its ring shape led to an interconnected co-ordination polymer, having transition metal ion nodes, with the appropriate co-ordinating functionalities (CO 2H). The Tröger's base-derived ligands were synthesized in two steps to generate ICPs.
KW - Gas separation
KW - Hydrogen storage
KW - Microparticles
KW - Porous materials
KW - Tröger's base
UR - http://www.scopus.com/inward/record.url?scp=58149469075&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=58149469075&partnerID=8YFLogxK
U2 - 10.1002/smll.200801160
DO - 10.1002/smll.200801160
M3 - Article
C2 - 19058289
AN - SCOPUS:58149469075
VL - 5
SP - 46
EP - 50
JO - Small
JF - Small
SN - 1613-6810
IS - 1
ER -