Traction characteristics of siloxanes with aryl and cyclohexyl branches

Thomas Zolper, Zhi Li, Manfred Jungk, Andreas Stammer, Herbert Stoegbauer, Tobin J Marks, Yip Wah Chung, Qian Wang

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

The molecular structures, rheological properties, and friction coefficients of several new siloxane-based polymers were studied to explore their traction characteristics. The molecular structures including branch content were established by nuclear magnetic resonance spectroscopy, while the molecular mass distributions were determined by gel permeation chromatography. Density, viscosity, elastohydrodynamic film formation, and friction were investigated over a temperature range of 303-398 K. Film thickness and friction measurements were studied under the conditions that are representative of boundary, mixed, and full-film lubrication regimes, aiming at maximizing traction performance and temperature stability by simultaneous optimization of the size and content of ring-shaped branch structures. This study provides quantitative insight into the effect of siloxane molecular structure on the tribological performance for traction drive applications such as continuously variable transmissions.

Original languageEnglish
Pages (from-to)301-311
Number of pages11
JournalTribology Letters
Volume49
Issue number2
DOIs
Publication statusPublished - Feb 2013

Fingerprint

Siloxanes
traction
siloxanes
Molecular structure
molecular structure
Friction
elastohydrodynamics
friction measurement
Elastohydrodynamics
gel chromatography
magnetic resonance spectroscopy
Gel permeation chromatography
Molecular mass
lubrication
mass distribution
coefficient of friction
Nuclear magnetic resonance spectroscopy
Lubrication
Film thickness
Polymers

Keywords

  • Continuously variable transmissions (CVT)
  • EHL friction (traction)
  • Silicones
  • Synthetic base stocks
  • Traction fluids

ASJC Scopus subject areas

  • Mechanical Engineering
  • Mechanics of Materials
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

Cite this

Zolper, T., Li, Z., Jungk, M., Stammer, A., Stoegbauer, H., Marks, T. J., ... Wang, Q. (2013). Traction characteristics of siloxanes with aryl and cyclohexyl branches. Tribology Letters, 49(2), 301-311. https://doi.org/10.1007/s11249-012-0066-x

Traction characteristics of siloxanes with aryl and cyclohexyl branches. / Zolper, Thomas; Li, Zhi; Jungk, Manfred; Stammer, Andreas; Stoegbauer, Herbert; Marks, Tobin J; Chung, Yip Wah; Wang, Qian.

In: Tribology Letters, Vol. 49, No. 2, 02.2013, p. 301-311.

Research output: Contribution to journalArticle

Zolper, T, Li, Z, Jungk, M, Stammer, A, Stoegbauer, H, Marks, TJ, Chung, YW & Wang, Q 2013, 'Traction characteristics of siloxanes with aryl and cyclohexyl branches', Tribology Letters, vol. 49, no. 2, pp. 301-311. https://doi.org/10.1007/s11249-012-0066-x
Zolper, Thomas ; Li, Zhi ; Jungk, Manfred ; Stammer, Andreas ; Stoegbauer, Herbert ; Marks, Tobin J ; Chung, Yip Wah ; Wang, Qian. / Traction characteristics of siloxanes with aryl and cyclohexyl branches. In: Tribology Letters. 2013 ; Vol. 49, No. 2. pp. 301-311.
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